Chemistry:Phosphide chloride

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A Phosphide chloride is a mixed anion compound containing both phosphide (P3−) and chloride (Cl−) ions. A common structural element is P73− which is called heptaphosphanortricyclane with a formal IUPAC name of heptaphosphatricyclo[2.2.1.02,6]heptane.[1]

Group 12 elements, cadmium and mercury are in most of the known compounds.

List

name formula formula
weight 		crystal
system 		space
group 		unit cell Å volume density comments ref
Ca3PCl3 cubic Pm3m a=5.713 Z=1 186.48 2.29 [2]
Cu6PS5Cl 607.96 cubic P43m a=9.6962 Z=4 911.6 4.430 red [3]
Sr2PCl cubic a=6.18 [4]
Sr2P7Cl monoclinic C2/c a=14.571 b=12.212 c=22.292 β=103.740° Z=16 3853 3.948 P73–, clusters [1]
Ag6PS5Cl cubic P43m a=10.3514 Z=4 1109.2 5.234 orange [3]
α-Cd3PCl3 hexagonal a=7.63 c=7.13 pale yellow >530 °C or quenched [5]
β-Cd3PCl3 monoclinic a=6.99 b=7.97 c=7.38 β=118.1° pale yellow <530 °C [5]
Cd4P2Cl3 617.89 cubic Pa3 a=12.1474 Z=8 1792.5 4.579 yellow; band gap 2.36 eV [6]
Cd2P3Cl monoclinic C2/c a=7.98 b=8.98 c=7.55 β= brown; band gap 1.87 [7]
Cd2PCl2 monoclinic P21/n a=7.736 b=8.957 c=7.880 β=118.92° Z=4 477.93 4.540 yellow [8][9]
Cd7P4Cl6 cubic Pa3 a=11.93 light green [7]
Ba2P7Cl monoclinic P21/m a = 11.726, b = 6.829, c = 6.337, β = 95.27°, Z = 2 P73–, clusters [1][10]
La3Zn4P6Cl orthorhombic Cmcm a= 4.0576 b 13.632 c 21.547 Z=4 1191.8 5.013 black; thermal conductivity 0.7 Wm−1 K−1 (low) [11][12]
Eu2PCl cubic Fm3m a = 6.106, Z = 2 [13]
W6PCl17 orthorhombic Imm2 a=6.7835 b=15.8762 c=10.0727 Z=2 1084.79 5.3168 black [14]
W4(PCl)Cl10 monoclinic C2/m a=13.257 b=9.850 c=11.400 β=91.38 Z=4 1488.2 5.161 black; chloro-phosphinidene ligand [14]
[Hg4P2][HfCl6] orthorhombic Pbca a=12.919 b=13.263 c=16.239 Z=8 2783 5.994 yellow [15]
Hg2PCl2 monoclinic I2/m a=7.643,b=7.977,c=8.539,β=115.23°,Z=4 469.8 7.113 yellow [16][17]
Hg2P3Cl monoclinic C2/c a = 7.834, b = 8.844, c = 7.591, β = 98.68°, Z = 4 [18]
[Hg6P4](TiCl6)Cl cubic Pa3 a=11.7675, Z=4 1627.2 6.627 black or dark brown [19]
(Hg6P4)(CrCl6)Cl 1627.57 cubic Pa3 a=11.7364 Z=4 1616.6 6.687 yellow; resistivity is humidity sensitive [20]
(Hg6P4)(CuCl3)2 monoclinic C2/c a=23.633 b=8.956 c=14.248 β =124.213° Z=6 2493.9 6.660 pinkish-red; ferroelectric below 37 K: 114 μC m−2 [21]
(Hg23P12)(ZnCl4)6 hexagonal P62m a=12.9774 c=11.749 Z=1 1713.6 6.035 yellow [22]
(Hg11P4)(GaCl4)4 monoclinic C2/m a=12.762 b=7.353 c=22.040 β=100.32 Z=2 2034.7 5.185 yellow [23]
[Hg4P2][ZrCl6] orthorhombic Pbca a=12.899 b=13.255 c=16.196 Z=8 2769.1 5.604 yellow [15]
Hg4Ag5P8Cl5 orthorhombic Cmcm a=11.1426 b=14.5064 c=11.8444 Z=4 1914.5 6.129 high temp [24]
Hg4Ag5P8Cl5 monoclinic C2/m a=14.490 b=10.904 c=6.2863 β=104.094 Z=2 963.4 6.090 [24]
[Hg6P4Cl3](SnCl3) cubic P213 a = 11.865 Z=4 [25]
(Hg6P4Cl3)(PbCl3) cubic P213 a=11.8837 Z=4 1678.24 6.916 yellow [22]

References

  1. ↑ 1.0 1.1 1.2 Dolyniuk, Juli-Anna; Tran, Nhon; Lee, Kathleen; Kovnir, Kirill (July 2015). "Sr 2 P 7 X ( X = Cl, Br, and I): Synthesis, Crystal and Electronic Structures of Double Zintl Salts Containing Heptaphosphanortricyclane, P 7 3-: Double Zintl Salts with Heptaphosphanortricyclane, P 7 3-" (in en). Zeitschrift für anorganische und allgemeine Chemie 641 (8–9): 1422–1427. doi:10.1002/zaac.201500140. https://onlinelibrary.wiley.com/doi/10.1002/zaac.201500140. 
  2. ↑ Hadenfeldt, C.; Herdejürgen, H. (October 1986). "Darstellung, kristallstruktur und thermisches verhalten der calciumphosphidchloride Ca2 − xP1 − xCl1+x (0 ⩽ x ⩽ 0,18) und Ca3PCl3" (in de). Journal of the Less Common Metals 124 (1–2): 93–103. doi:10.1016/0022-5088(86)90480-7. https://linkinghub.elsevier.com/retrieve/pii/0022508886904807. 
  3. ↑ 3.0 3.1 Gao, Lihua; Wu, Xiaowen; Yang, Daqing; Tian, Xinyu; Xu, Jingjing; Zhang, Bingbing; Wu, Kui (2021). "M 6 PS 5 X (M = Ag, Cu; X = Cl, Br) chalcohalides exhibiting strong nonlinear optical responses and high laser damage resistances" (in en). Dalton Transactions 50 (48): 17901–17905. doi:10.1039/D1DT03251H. ISSN 1477-9226. PMID 34851337. http://xlink.rsc.org/?DOI=D1DT03251H. 
  4. ↑ Hadenfeldt, Claus (1976-04-01). "Darstellung und Eigenschaften von Ca 2 AsBr, Sr 2 AsCl und Ca 3 AsBr 3 .: Preparation and Properties of Ca 2 AsBr, Sr 2 AsCl, and Ca 3 AsBr 3" (in en). Zeitschrift für Naturforschung B 31 (4): 408–410. doi:10.1515/znb-1976-0403. ISSN 1865-7117. 
  5. ↑ 5.0 5.1 Breitinger, Dietrich; Herrmann, Wolfgang A.; Hiller, Wolfgang (14 May 2014) (in en). Synthetic Methods of Organometallic and Inorganic Chemistry, Volume 5, 1999: Volume 5: Copper, Silver, Gold, Zinc, Cadmium and Mercury. Georg Thieme Verlag. p. 177. ISBN 978-3-13-179211-2. https://books.google.com/books?id=riaGAwAAQBAJ. 
  6. ↑ Roy, Anand; Shenoy, U. Sandhya; Manjunath, K.; Vishnoi, Pratap; Waghmare, Umesh V.; Rao, C. N. R. (2016-07-21). "Structure and Properties of Cd 4 P 2 Cl 3 , an Analogue of CdS" (in en). The Journal of Physical Chemistry C 120 (28): 15063–15069. doi:10.1021/acs.jpcc.6b04058. ISSN 1932-7447. https://pubs.acs.org/doi/10.1021/acs.jpcc.6b04058. 
  7. ↑ 7.0 7.1 Roy, Anand; Singh, Anjali; Aravindh, S. Assa; Servottam, Swaraj; Waghmare, Umesh V.; Rao, C. N. R. (2019-05-20). "Structural Features and HER activity of Cadmium Phosphohalides" (in en). Angewandte Chemie International Edition 58 (21): 6926–6931. doi:10.1002/anie.201900936. ISSN 1433-7851. PMID 30908780. https://onlinelibrary.wiley.com/doi/10.1002/anie.201900936. 
  8. ↑ Olenev, A. V. (March 2003). "Synthesis, crystal and electronic structure of Cd2PCl2: influence of cation on characteristic structural features of pnictide halides of Group 12 metals". Russian Chemical Bulletin 52 (3): 570–575. doi:10.1023/A:1023938202282. http://link.springer.com/10.1023/A:1023938202282. 
  9. ↑ Olenev, A. V. (2003). "Synthesis, crystal and electronic structure of Cd2PCl2: influence of cation on characteristic structural features of pnictide halides of Group 12 metals". Russian Chemical Bulletin 52 (3): 570–575. doi:10.1023/A:1023938202282. http://link.springer.com/10.1023/A:1023938202282. 
  10. ↑ Schnering, Hans Georg V.; Menge, Günter (October 1981). "Zur Chemie und Strukturchemie der Phosphide und Polyphosphide. 26. Dibariumheptaphosphidchlorid Ba2P7Cl, eine Verbindung mit dem polycyclischen Anion P73?". Zeitschrift für anorganische und allgemeine Chemie 481 (10): 33–40. doi:10.1002/zaac.19814811005. 
  11. ↑ Wang, Jian; Kaseman, Derrick; Lee, Kathleen; Sen, Sabyasachi; Kovnir, Kirill (2016-07-12). "Enclathration of X@La 4 Tetrahedra in Channels of Zn–P Frameworks in La 3 Zn 4 P 6 X (X = Cl, Br)" (in en). Chemistry of Materials 28 (13): 4741–4750. doi:10.1021/acs.chemmater.6b01752. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/acs.chemmater.6b01752. 
  12. ↑ Dolyniuk, Juli-Anna; Kovnir, Kirill (2013-08-26). "Zintl Salts Ba2P7X (X = Cl, Br, and I): Synthesis, Crystal, and Electronic Structures" (in en). Crystals 3 (3): 431–442. doi:10.3390/cryst3030431. ISSN 2073-4352. 
  13. ↑ Hadenfeldt, C.; Held, W. (September 1986). "Darstellung, eigenschaften und kristallstruktur der Europium(ii)-phosphidhalogenide Eu2PCl, Eu2PBr und Eu2PI" (in de). Journal of the Less Common Metals 123 (1–2): 25–35. doi:10.1016/0022-5088(86)90111-6. https://linkinghub.elsevier.com/retrieve/pii/0022508886901116. 
  14. ↑ 14.0 14.1 Ströbele, Markus; Eichele, Klaus; Meyer, H.‐Jürgen (September 2011). "Phosphorus‐Centered and Phosphinidene‐Capped Tungsten Chloride Clusters" (in en). European Journal of Inorganic Chemistry 2011 (26): 4063–4068. doi:10.1002/ejic.201100122. ISSN 1434-1948. https://onlinelibrary.wiley.com/doi/10.1002/ejic.201100122. 
  15. ↑ 15.0 15.1 Li, Xiao‐Guo; Jiang, Xiao‐Ming; Zhang, Ming‐Jian; Liu, Bin‐Wen; Fan, Yu‐Hang; Guo, Guo‐Cong; Huang, Jin‐Shun (2013-12-02). "Three‐Dimensional Mercury Pnictide [Hg 4 Z 2 2+ Cationic Frameworks Stabilized by Tetravalent Metal Halide Anions in Supramolecular Complexes: [Hg 4 Z 2 ][MCl 6 ] (Z = P, As; M = Zr, Hf)"] (in en). European Journal of Inorganic Chemistry 2013 (35): 5980–5986. doi:10.1002/ejic.201300888. ISSN 1434-1948. https://onlinelibrary.wiley.com/doi/10.1002/ejic.201300888. 
  16. ↑ Breitinger, Dietrich; Herrmann, Wolfgang A.; Hiller, Wolfgang (14 May 2014) (in en). Synthetic Methods of Organometallic and Inorganic Chemistry, Volume 5, 1999: Volume 5: Copper, Silver, Gold, Zinc, Cadmium and Mercury. Georg Thieme Verlag. p. 207. ISBN 978-3-13-179211-2. https://books.google.com/books?id=riaGAwAAQBAJ. 
  17. ↑ Olenev, Andrei V.; Shevelkov, Andrei V.; Popovkin, Boris A. (January 1999). "Crystal Structure of Hg2PCl2and Electronic Structure of Its Main "Building Unit"—The (P2Hg6) Octahedron" (in en). Journal of Solid State Chemistry 142 (1): 14–18. doi:10.1006/jssc.1998.7977. Bibcode: 1999JSSCh.142...14O. https://linkinghub.elsevier.com/retrieve/pii/S0022459698979774. 
  18. ↑ Shevelkov, A. V.; Dikarev, E. V.; Popovkin, B. A. (1994-07-01). Shevelkov, A. V.; Dikarev, E. V.; Popovkin, B. A.. eds. "Helical [unk(P 1− ) chains in the structures of Hg 2 P 3 Br and Hg 2 P 3 Cl"] (in en). Zeitschrift für Kristallographie - Crystalline Materials 209 (7): 583–585. doi:10.1524/zkri.1994.209.7.583. ISSN 2194-4946. Bibcode: 1994ZK....209..583S. https://www.degruyter.com/document/doi/10.1524/zkri.1994.209.7.583/html. 
  19. ↑ Olenev, Andrei V.; Shevelkov, Andrei V. (August 2001). "Synthesis, Structure, and Properties of [Hg6P4(TiCl6)Cl: The Problem of Host–Guest Interactions"] (in en). Journal of Solid State Chemistry 160 (1): 88–92. doi:10.1006/jssc.2001.9196. Bibcode: 2001JSSCh.160...88O. https://linkinghub.elsevier.com/retrieve/pii/S0022459601991960. 
  20. ↑ Peng, Si-Yan; Yang, Liu-Sai; Yao, Ming-Shui; Yu, Le-Shu (2018). "A new pnictidehalide with van der Waals host–guest interactions exhibiting both geometric spin frustration and resistive humidity sensitivity" (in en). New Journal of Chemistry 42 (3): 1787–1795. doi:10.1039/C7NJ03351F. ISSN 1144-0546. http://xlink.rsc.org/?DOI=C7NJ03351F. 
  21. ↑ Jiang, Xiao-Ming; Yan, Zhi-Bo; Liu, Dan; Wang, Jing-Xue; Liu, Mei-Feng; Guo, Guo-Cong; Jin, Biao-Bing; Li, Xiao-Guang et al. (December 2013). "Ferroelectric Transition in the Inorganic Supramolecular Complex (Hg 6 P 4 )(CuCl 3 ) 2" (in en). Chemistry: An Asian Journal 8 (12): 2925–2931. doi:10.1002/asia.201301040. PMID 24006192. https://onlinelibrary.wiley.com/doi/10.1002/asia.201301040. 
  22. ↑ 22.0 22.1 Jiang, Xiao-Ming; Wang, Guan-E; Liu, Zhi-Fa; Zhang, Ming-Jian; Guo, Guo-Cong (2013-08-05). "Large Mid-IR Second-Order Nonlinear-Optical Effects Designed by the Supramolecular Assembly of Different Bond Types without IR Absorption" (in en). Inorganic Chemistry 52 (15): 8865–8871. doi:10.1021/ic401056t. ISSN 0020-1669. PMID 23837877. https://pubs.acs.org/doi/10.1021/ic401056t. 
  23. ↑ Jiang, Xiao-Ming; Li, Xiao-Guo; Fan, Yu-Hang; Liu, Bin-Wen; Zeng, Hui-Yi; Guo, Guo-Cong (2013). "New mercury-contained cationic frameworks stabilized by (GaCl4)− unit via weak electrostatic forces in supramolecular compounds (Hg11P4)(GaCl4)4 and (Hg3AsS)(GaCl4)" (in en). Dalton Transactions 42 (43): 15475–15481. doi:10.1039/c3dt51451j. ISSN 1477-9226. PMID 24022795. http://xlink.rsc.org/?DOI=c3dt51451j. 
  24. ↑ 24.0 24.1 Oleneva, Olga S.; Shestimerova, Tatiana A.; Dikarev, Evgeny V.; Shevelkov, Andrei V. (2006-11-27). "P88− Polyanion with Phosphorus Atoms in Three Different Formal Oxidation States Stabilized by a Combination of Ag+ and Hg2+ Cations" (in de). Angewandte Chemie 118 (46): 7883–7886. doi:10.1002/ange.200601155. Bibcode: 2006AngCh.118.7883O. https://onlinelibrary.wiley.com/doi/10.1002/ange.200601155. 
  25. ↑ Olenev, Andrei V.; Baranov, Alexei I.; Shevelkov, Andrei V.; Popovkin, Boris A. (2002). "A New Family of Supramolecular Complexes with 3D Cationic Hg/Z Frameworks, SnX3− Guest Anions (Z = P, as, Sb; X = Cl, Br, I): Crystal Structures and Host−Guest Interactions". European Journal of Inorganic Chemistry 2002 (3): 547–553. doi:10.1002/1099-0682(200203)2002:3<547::AID-EJIC547>3.0.CO;2-N. 



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