Chemistry:Perbromyl fluoride
From HandWiki
| Names | |
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| Other names
Bromine fluoride trioxide
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| Identifiers | |
3D model (JSmol)
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PubChem CID
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| Properties | |
| BrFO3 | |
| Molar mass | 146.899 g·mol−1 |
| Appearance | colorless gas |
| Melting point | −9 °C (16 °F; 264 K) |
| reacts with water | |
| Related compounds | |
Related compounds
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Periodyl fluoride Perchloryl fluoride |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Tracking categories (test):
Perbromyl fluoride is an inorganic compound of bromine, fluorine, and oxygen with the chemical formula BrO
3F.[1][2]
Synthesis
Synthesis if perbromyl fluoride is by the effect of antimony pentafluoride on a solution of potassium perbromate in hydrofluoric acid:[3]
- KBrO
4 + 2SbF
5 + 3HF → BrO
3F + K[SbF
6] + H[SbF
6]•H
2O
- KBrO
Physical properties
Perbromyl fluoride forms a colorless gas that is stable in the absence of moisture.[4]
Chemical properties
Perbromyl fluoride reacts with water:
- BrO
3F + H
2O → HBrO
4 + HF
- BrO
References
- ↑ Johnson, Gerald K.; O'Hare, P. A. G.; Appelman, Evan H. (1972). Perbromyl fluoride. 11. NIST. pp. 800–802. doi:10.1021/ic50110a028. https://webbook.nist.gov/cgi/formula?ID=C25251030&Mask=4. Retrieved 5 June 2023.
- ↑ Appleman, Evan H.; Studier, Martin H. (July 1969). "Perbromyl fluoride" (in en). Journal of the American Chemical Society 91 (16): 4561–4562. doi:10.1021/ja01044a049. ISSN 0002-7863. https://pubs.acs.org/doi/10.1021/ja01044a049. Retrieved 5 June 2023.
- ↑ Steudel, Ralf (20 April 2011) (in en). Chemistry of the Non-Metals: With an Introduction to Atomic Structure and Chemical Bonding. Walter de Gruyter. p. 265. ISBN 978-3-11-083082-8. https://books.google.com/books?id=Z7_-lFZbxi0C&dq=perBromyl+fluoride&pg=PA265. Retrieved 5 June 2023.
- ↑ (in en) U. S. Atomic Energy Commission Division of Plans and Atomic Energy Research: Life and Physical Sciences, Reactor Development, Waste Management. U.S. Government Printing Office. 1970. p. 10. https://books.google.com/books?id=mYvvAAAAMAAJ&dq=perBromyl+fluoride&pg=RA1-PA10. Retrieved 5 June 2023.
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