Chemistry:Nitride chloride

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A chloride nitride is a mixed anion compound containing both chloride (Cl−) and nitride ions (N3−). Another name is metallochloronitrides. They are a subclass of halide nitrides or pnictide halides.[1] The group 4 element chloride nitrides can be intercalated by alkali metals that supply extra electrons, and other molecules such as from solvents like tetrahydrofuran, yielding layered substances that are superconductors. A superconductor transition temperature Tc of 25.5K has been achieved.[2]

Production

Nitride chlorides may be produced by heating metal nitrides with metal chlorides. The ammonolysis process heats a metal chloride with ammonia.[3] A related method heats a metal or metal hydride with ammonium chloride. The nitrogen source could also be an azide or an amide.[3]

List

name formula formula
weight 		crystal
system 		space
group 		unit cell Å volume density comments ref
Li4NCl hexagonal R3 a=366.225 c=1977.18 Z=3 [4]
Li1.8N0.4Cl0.6 Li ion conductor [5]
Cyanogen chloride ClCN molecular
Magnesium nitride chloride Mg2NCl hexagonal R3m a = 3.2994 c = 17.857 [6]
phosphonitrilic chloride cyclic trimer P3N3Cl6 molecular
trithiazyl trichloride S3N3Cl3 cas 5964-00-1 [7]
Ca2NCl hexagonal R3m a 3.6665 c 19.7187 [8]
Sc2Cl2N P3m1 a = 3:517 c = 8.813 layered [1]
Sc4Cl6N orthorhombic Pbam a = 11.625, b = 12.118, c = 3.5447 [1]
Sc5Cl8N C2/m a = 17.85, b = 3.5505, c = 12.090, β = 130.13 [1]
Sc7Cl12N R3 a = 12.990, c = 8.835 Sc6N clusters [1]
Titanium nitride chloride TiNCl orthorhombic Pmmn a=3.275 b=3.967 c=8.402

a = 3.937, b = 3.258, c = 7.803

109.2 black [9]
Li0.6TiNCl [9]
Cl3VNCl triclinic P1 a = 7.64, b = 7.14, c = 5.91, α = 94.9, β = 112.4, γ = 107.8 V=NCl complex [1]
Zn2NCl 180.20 orthorhombic Pna21 a=6.137 b=7.394 c=5.940 Z=4 269.5 4.441 band gap 3.21 eV [10]
Zn2NCl orthorhombic Pnma Z=16 predicted [11]
Zn2NCl hexagonal R3m predicted [11]
Sr2BN2Cl [12]
α-Y2Cl3N orthorhombic Pbcn a = 12.761, b = 6.676, c = 6.1000 [1]
β-Y2Cl3N C2/m a = 15.248, b = 3.8520, c = 10.157, β = 118.41 [1]
α-ZrNCl orthorhombic Pmmn a = 3.937, b = 3.258, c = 7.803 pale yellow-green [1]
β-zirconium nitride chloride β-ZrNCl hexagonal R3m a = 3.6031, c = 27.672 yellow-green;semiconductor; layers of Cl–Zr–N–N–Zr–Cl [13][1]
Zr6Cl15N cubic Ia3d a = 21.171 [1]
Lithium-intercalated β-zirconium nitride chloride LixZrNCl black; superconductor Tc=12.5 K [14]
NaxZrNCl superconductor Tc 15 K [13]
KxZrNCl superconductor Tc 15 K [13]
molybdenum nitride chloride MoNCl3 triclinic P1 a = 9.14, b = 7.67, c = 8.15, α = 108.8, β = 99.3, γ= 108.6 [15][1]
Mo2NCl7 triclinic P1 a = 9.057, b = 9.754, c = 12.834, α = 103.13, β = 109.83, γ = 98.58 [1]
Mo2NCl8 monoclinic P2/c a = 9.961, b = 6.294, c = 17.808, β = 101.82 [1]
Phenyldiazonium tetrachloronitridomolybdate C6H5N2[MoNCl4] monoclinic P21/c a = 12.83, b = 11.70, c = 19.22 β = 94.11 Z=2 dark red [15]
Technetium chloride nitride TcCl3N black; cas 154525-32-3 [7]
(Ph4As)[TcNCl4] [16]
[Se3N2Cl]+SbCl6- triclinic P1 a=6.982 b=6.997 c=15.105 α = 89.45°, β = 86.18°, γ = 68.22° Z=2 red [17]
Ba2NCl hexagonal R3m
Ba3Si3N5OCl P62c a=9.560 c=5.552 [18]
Ba25Nb5N19Cl18 [1]
LiBa4[Mo2N7]BaCl2 [1]
La2NCl3 orthorhombic Ibam a = 13.758, b = 6.922, c = 6.185 [19]
La2Cl(CN2)N orthorhombic Cmmm a = 13.340, b = 9.5267, c = 3.9402, Z=4 [20]
La6N3S4Cl orthorhombic Pnma a = 11.597; b = 4.1095; c = 27.568 Z=4 [21]
CeNCl tetragonal P4/nmm a=4.079 c=6.837 Z= black [22]
Cerium(III) nitride chloride Ce2NCl3 orthorhombic Ibam a = 13.6021 b=6.8903 c= 6.1396 Z=4 575.42 4.624 Light yellow [23]
Ce2Cl(CN2)N orthorhombic Cmmm a = 13.3914, b = 9.6345, c = 3.9568, Z=4 [20]
Ce6Cl12N2 1294.1 monoclinic P21/c a=11.233 b=16.527 c=10.798 β =90.15 Z=4 1988 4.324 yellow [22]
Na2[{(ON)Ce4}Cl9] monoclinic P21/m a = 8.1321, b = 11.4613, c = 9.4286 and β = 107.504° Z=2 [24]
Pr2NCl3 orthorhombic Ibam a = 13.531, b = 6.8512, c = 6.1072 [19]
Pr5N3S2Cl2 monoclinic C2/m a = 15.402; b = 4.0092; c = 16.563; β = 101.24°, Z = 4 [25]
Pr6N3S4Cl orthorhombic Pnma a=11.3987 b=4.0235 c=26.999 Z=4 1238.3 reddish-brown [26]
Nd2NCl3 orthorhombic Pbcn a = 13.382, b = 6.8462, c = 6.1815 [19]
Nd3NCl6 orthorhombic Pbca a = 10.4971, b = 11.0683, c = 16.211; Z = 8 [27]
Nd4NS3Cl3 hexagonal P63mc a = 9.2278, c = 6.8306; Z = 2 [27]
Nd6N3S4Cl orthorhombic Pnma a = 11.371; b = 3.9934; c = 26.876 [21]
Na2Nd4ONCl9 monoclinic P21/m a = 8.0354, b = 11.3426, c = 9.2831 and β = 107.109° [28]
Trigadolinium hexachloride nitride Gd3Cl6N 698.485 triclinic P1 a = 7.107, b = 8.156, c = 9.707, α = 75.37°, β = 109.10°, γ = 114.64° Z=2 478.8 4.84 colourless; water sensitive; biaxial (−) [29]
Gd2NCl3 orthorhombic Pbcn a=13.017 b=6.7310 c=6.1403 [19]
Gd2N2Cl tetragonal P4mm a = 4.25 c = 5.92 [30]
α-HfNCl orthorhombic Pmmn a = 4.130, b = 3.497, c = 8.070 [31][1]
β-HfNCl hexagonal R3m a = 3.5744, c = 27.7075 colourless [1]
NaxHfNCl superconductor Tc 25 K [32]
Ba3Ta3N6Cl P62c a =10.1455 c =5.9770 [18]
Ba3Cl2TaN3 hexagonal P63cm a = 15.0739, c = 6.3298; Z = 6 light yellow [33]
Ba15Ta15N33Cl4 P62c a =10.1545 c =29.917 [18]
W2NCl8 triclinic P1 a = 6.2423, b = 6.309, c = 6.931, α = 89.76, β = 81.51, γ = 82.68 [1]
W2NCl9 P21/c a = 8.421, b = 16.786, c = 11.930, β = 134.74° [1]
[WNCl3 • POCl3]4 • 2 POCl3 triclinic P1 a = 12.257 b = 11.851 c = 19.27.0 α = 102.6° β= 108.4° γ = 94.8° Z=2 [34]
Ba4[WN4]Cl2 [1]
ReNCl4 tetragonal I4 a=8.278 b=8.281 c=4.057 Z=2 brown [35][36]
ReNCl4·H2O orthorhombic Pnma a = 10.754, b = 11.085, c = 547.7 Z=4 red [36]
[NBu4][ReNCl4] orthorhombic P4/n a 11.795 b 11.795 c 8.466 ReN triple bond in complex [37]
K2OsNCl5 orthorhombic Pnma a = 13.27, b = 9.85, c = 6.84 [1]
Kleinite Hg2N(Cl,SO4)•n(H2O) hexagonal C63/mmc a = 13.56 c = 11.13 Z = 18 1,772.33 8.01 yellow [38]
Mosesite Hg2N(Cl,SO4,MoO4,CO3)•(H2O) cubic F43m a = 9.524, Z = 8 863.89 7.71 yellow; refractive index 2.065 [39]
ThNCl tetragonal P4/nmm a =4.09486 c =6.9013 [40]
Uranium nitride chloride UNCl tetragonal P4/nmm a=3.97 c=6.81 Z=2 [41]

References

  1. ↑ 1.00 1.01 1.02 1.03 1.04 1.05 1.06 1.07 1.08 1.09 1.10 1.11 1.12 1.13 1.14 1.15 1.16 1.17 1.18 1.19 1.20 1.21 Headspith, David A.; Francesconi, M. Grazia (October 2009). "Transition Metal Pnictide-Halides: A Class of Under-Explored Compounds" (in en). Topics in Catalysis 52 (11): 1611–1627. doi:10.1007/s11244-009-9282-5. ISSN 1022-5528. http://link.springer.com/10.1007/s11244-009-9282-5. 
  2. ↑ Yamanaka, Shoji (2010). "Intercalation and superconductivity in ternary layer structured metal nitride halides (MNX: M = Ti, Zr, Hf; X = Cl, Br, I)" (in en). Journal of Materials Chemistry 20 (15): 2922. doi:10.1039/b922149b. ISSN 0959-9428. http://xlink.rsc.org/?DOI=b922149b. 
  3. ↑ 3.0 3.1 Schurz, Christian M.; Shlyk, Larysa; Schleid, Thomas; Niewa, Rainer (January 2011). "Superconducting nitride halides MNX (M = Ti, Zr, Hf; X = Cl, Br, I)". Zeitschrift für Kristallographie 226 (4): 395. doi:10.1524/zkri.2011.1350. ISSN 0044-2968. Bibcode: 2011ZK....226..395S. 
  4. ↑ Marx, Rupert (February 1997). "Preparation and Crystal Structure of Lithium Nitride Chloride Li4NCl" (in en). Journal of Solid State Chemistry 128 (2): 241–246. doi:10.1006/jssc.1996.7196. Bibcode: 1997JSSCh.128..241M. https://linkinghub.elsevier.com/retrieve/pii/S0022459696971960. 
  5. ↑ Hartwig, P.; Weppner, W.; Wichelhaus, W. (April 1979). "Fast ionic lithium conduction in solid lithium nitride chloride" (in en). Materials Research Bulletin 14 (4): 493–498. doi:10.1016/0025-5408(79)90191-0. https://linkinghub.elsevier.com/retrieve/pii/0025540879901910. 
  6. ↑ Li, Yanqing; George, Janine; Liu, Xiaohui; Dronskowski, Richard (February 2015). "Synthesis, Structure Determination and Electronic Structure of Magnesium Nitride Chloride, Mg 2 NCl: Magnesium Nitride Chloride, Mg 2 NCl" (in en). Zeitschrift für anorganische und allgemeine Chemie 641 (2): 266–269. doi:10.1002/zaac.201400496. 
  7. ↑ 7.0 7.1 Macintyre, Jane E. (1995-10-12) (in en). Dictionary of Inorganic Compounds, Supplement 3. CRC Press. pp. 274. ISBN 978-0-412-49110-8. https://books.google.com/books?id=YY2N7nOhBoIC&pg=PA274. 
  8. ↑ Bowman, Amy; Smith, Ronald I.; Gregory, Duncan H. (June 2005). "Ternary and quaternary layered nitride halides, Ca2N(X,X′) (X,X′=Cl, Br, I): Evolution of structure with composition" (in en). Journal of Solid State Chemistry 178 (6): 1807–1817. doi:10.1016/j.jssc.2005.03.021. Bibcode: 2005JSSCh.178.1807B. https://linkinghub.elsevier.com/retrieve/pii/S0022459605001118. 
  9. ↑ 9.0 9.1 Kuhn, A.; Hoppe, H.; Strähle, J.; Garcı́a-Alvarado, F. (2004). "Electrochemical Lithium Intercalation in Titanium Nitride Chloride" (in en). Journal of the Electrochemical Society 151 (6): A843. doi:10.1149/1.1740782. Bibcode: 2004JElS..151A.843K. https://iopscience.iop.org/article/10.1149/1.1740782. 
  10. ↑ Zhao, Xin; Lin, Chensheng; Chen, Jindong; Luo, Min; Xu, Feng; Yang, Shunda; Shi, Shuangshuang; Li, Bingxuan et al. (2021-02-23). "Halonitrides Zn 2 NX (X=Cl,Br): Novel Mid-Infrared Nonlinear Optical Materials" (in en). Chemistry of Materials 33 (4): 1462–1470. doi:10.1021/acs.chemmater.0c04772. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/acs.chemmater.0c04772. 
  11. ↑ 11.0 11.1 Li, Xiaofeng; Tao, Yaping; Lv, Jian; Hu, Ziyu; Liu, Zhong-Li (August 2015). "Pressure-induced phase transition of zinc nitride chlorine" (in en). Computational Materials Science 106: 175–179. doi:10.1016/j.commatsci.2015.04.043. https://linkinghub.elsevier.com/retrieve/pii/S0927025615002815. 
  12. ↑ Wang, Haoyang; Li, Zebin; Kang, Runtian; Ji, Ruijie; Wang, Yuhua (2022-11-14). "Sr 2 BN 2 Cl:Eu 2+ -Based Narrow-Band Blue-Emitting Phosphor: A Potential Color Converter for Illumination and Displays" (in en). Inorganic Chemistry 61 (45): 18245–18252. doi:10.1021/acs.inorgchem.2c03069. ISSN 0020-1669. PMID 36373304. https://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.2c03069. 
  13. ↑ 13.0 13.1 13.2 Kawaji, Hitoshi; Hotehama, Ken-ichi; Yamanaka, Shoji (1997-10-01). "Superconductivity of Alkali Metal Intercalated β-Zirconium Nitride Chloride, A x ZrNCl (A = Li, Na, K)" (in en). Chemistry of Materials 9 (10): 2127–2130. doi:10.1021/cm970211b. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/cm970211b. 
  14. ↑ Yamanaka, Shoji; Kawaji, Hitoshi; Hotehama, Ken-ichi; Ohashi, Masao (September 1996). "A new layer-structured nitride superconductor. Lithium-intercalated ?-zirconium nitride chloride, LixZrNCl" (in en). Advanced Materials 8 (9): 771–774. doi:10.1002/adma.19960080917. ISSN 0935-9648. https://onlinelibrary.wiley.com/doi/10.1002/adma.19960080917. 
  15. ↑ 15.0 15.1 Mueller, U.; Kujanek, R.; Dehnicke, K. (1982). "Molybdenum-nitride-trichloride-di-n-butylether [MoNCl3 . O(C4H9)24; preparation, i.r. spectrum, and crystal structure"] (in German). Zeitschrift für anorganische und allgemeine Chemie 495: 127–134. ISSN 0044-2313. http://inis.iaea.org/Search/search.aspx?orig_q=RN:14763782. 
  16. ↑ Abram, U.; Wollert, R. (1993). "The synthesis of TcNCl3; new approaches to TcNCl-4" (in English). Radiochimica Acta 63: 149–151. doi:10.1524/ract.1993.63.special-issue.149. ISSN 0033-8230. http://inis.iaea.org/Search/search.aspx?orig_q=RN:25030486. 
  17. ↑ Lau, Carsten; Neumüller, Bernhard; Dehnicke, Kurt (1997-04-01). "Synthese und Kristallstruktur von [Se 3 N 2 Cl + SbCl 6 - / Synthesis and Crystal Structure of [Se 3 N 2 Cl] + SbCl 6 -"] (in en). Zeitschrift für Naturforschung B 52 (4): 543–545. doi:10.1515/znb-1997-0416. ISSN 1865-7117. https://www.degruyter.com/document/doi/10.1515/znb-1997-0416/html. 
  18. ↑ 18.0 18.1 18.2 Barnes, Andrew J. D.; Prior, Timothy J.; Francesconi, M. Grazia (2007). "Zeolite-like nitride–chlorides with a predicted topology" (in en). Chemical Communications (44): 4638–4640. doi:10.1039/b712110e. ISSN 1359-7345. PMID 17989817. http://xlink.rsc.org/?DOI=b712110e. 
  19. ↑ 19.0 19.1 19.2 19.3 Uhrlandt, Stefan; Meyer, Gerd (July 1995). "Nitride chlorides of the early lanthanides: [M2NCl3(M=LaNd)"] (in en). Journal of Alloys and Compounds 225 (1–2): 171–173. doi:10.1016/0925-8388(94)07028-8. https://linkinghub.elsevier.com/retrieve/pii/0925838894070288. 
  20. ↑ 20.0 20.1 Srinivasan, Radhakrishnan; Ströbele, Markus; Meyer, H.-Jürgen (2003-06-01). "Chains of [RE 6 Octahedra Coupled by (NCN) Links in the Network Structure of RE 2 Cl(CN 2 )N. Synthesis and Structure of Two Novel Rare Earth Chloride Carbodiimide Nitrides with Structures Related to the RE 2 Cl 3 Type"] (in en). Inorganic Chemistry 42 (11): 3406–3411. doi:10.1021/ic020685z. ISSN 0020-1669. PMID 12767174. https://pubs.acs.org/doi/10.1021/ic020685z. 
  21. ↑ 21.0 21.1 Lissner, Falk; Schleid, Thomas; Meyer, Monika (February 1996). "Nitridsulfidchloride der Lanthanide: II. Der Formeltyp M6N3S4Cl (M = La?Nd)" (in de). Zeitschrift für anorganische und allgemeine Chemie 622 (2): 275–282. doi:10.1002/zaac.19966220213. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.19966220213. 
  22. ↑ 22.0 22.1 Ehrlich, Grant M.; Badding, M.E.; Brese, Nathaniel E.; Trail, Steven S.; DiSalvo, F.J. (April 1994). "New cerium nitride chlorides: Ce6Cl12N2 and CeNCl" (in en). Journal of Alloys and Compounds 206 (1): 95–101. doi:10.1016/0925-8388(94)90015-9. 
  23. ↑ Schurz, Christian M.; Schleid, Thomas (2011-07-15). "A-type Ce 2 NCl 3". Acta Crystallographica Section E 67 (7): i42. doi:10.1107/S1600536811023105. ISSN 1600-5368. PMID 21836827. PMC 3151823. http://scripts.iucr.org/cgi-bin/paper?S1600536811023105. 
  24. ↑ Schurz, Christian M.; Meyer, Monika; Meyer, Gerd; Schleid, Thomas (2010-05-25). "A New Example of the Structure Type A2[{Z2R4}X9: Synthesis and Crystal Structure of Na2[{(ON)Ce4}Cl9]"] (in en). Zeitschrift für anorganische und allgemeine Chemie 636 (7): 1169–1171. doi:10.1002/zaac.201000111. https://onlinelibrary.wiley.com/doi/10.1002/zaac.201000111. 
  25. ↑ Lissner, Falk; Schleid, Thomas (November 1997). "Nitridsulfidchloride der Lanthanide: III. Synthese und Kristallstruktur von Pr5N3S2Cl2" (in de). Zeitschrift für anorganische und allgemeine Chemie 623 (11): 1747–1752. doi:10.1002/zaac.19976231114. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.19976231114. 
  26. ↑ Meyer, M.; Schleid, Th. (1999-03-01). "Crystal structure of hexapraseodymium(III) trinitride tetrasulfide chloride, Pr6N3S4Cl". Zeitschrift für Kristallographie – New Crystal Structures 214 (1): 23–24. doi:10.1515/ncrs-1999-0116. ISSN 2197-4578. 
  27. ↑ 27.0 27.1 Meyer, Monika; Lissner, Falk; Schleid, Thomas (2000). "Nd3NCl6 und Nd4NS3Cl3: Zwei Neodymnitrid-Derivate mit diskreten Einheiten kantenverknüpfter ([N2Nd612+) bzw. isolierter [NNd4]9+-Tetraeder"] (in de). Zeitschrift für anorganische und allgemeine Chemie 626 (5): 1205–1210. doi:10.1002/(SICI)1521-3749(200005)626:5<1205::AID-ZAAC1205>3.0.CO;2-T. ISSN 1521-3749. https://onlinelibrary.wiley.com/doi/abs/10.1002/%28SICI%291521-3749%28200005%29626%3A5%3C1205%3A%3AAID-ZAAC1205%3E3.0.CO%3B2-T. 
  28. ↑ Schurz, Christian M.; Schleid, Thomas (October 2009). "Chains of trans-edge connected [ZM4 tetrahedra (Z=N and O) in the lanthanide nitride chlorides M2NCl3 and Na2M4ONCl9 (M=La–Nd)"] (in en). Journal of Alloys and Compounds 485 (1–2): 110–118. doi:10.1016/j.jallcom.2009.06.097. https://linkinghub.elsevier.com/retrieve/pii/S0925838809012328. 
  29. ↑ Simon, A.; Koehler, T. (February 1986). "A new gadolinium nitride chloride—Gd3Cl6N". Journal of the Less Common Metals 116 (1): 279–292. doi:10.1016/0022-5088(86)90236-5. 
  30. ↑ Chen, Ning; Liu, Xiuxia; Liu, Yang; Li, Yang (March 2013). "Study on novel rare-earth nitride chlorides GdNCl and Gd2N2Cl" (in en). APS March Meeting Abstracts 2013: Q1.299. Bibcode: 2013APS..MAR.Q1299C. https://ui.adsabs.harvard.edu/abs/2013APS..MAR.Q1299C/abstract. 
  31. ↑ Felser, Claudia; Seshadri, Ram (1999). "Electronic structures and instabilities of ZrNCl and HfNCl: implications for superconductivity in the doped compounds". Journal of Materials Chemistry 9 (2): 459–464. doi:10.1039/a808127a. http://xlink.rsc.org/?DOI=a808127a. 
  32. ↑ Weht, R.; Filippetti, A.; Pickett, W. E. (1999-11-01). "Electron doping in the honeycomb bilayer superconductors (Zr, Hf)NCl" (in en). EPL (Europhysics Letters) 48 (3): 320. doi:10.1209/epl/i1999-00484-4. ISSN 0295-5075. Bibcode: 1999EL.....48..320W. https://iopscience.iop.org/article/10.1209/epl/i1999-00484-4/meta. 
  33. ↑ Blaschkowski, Björn; Dürr, Oliver; Reckeweg, Olaf; Schleid, Thomas (July 2015). "Crystal Growth and Structure of the Barium Chloride Nitridotantalate(V) Ba 3 Cl 2 TaN 3" (in en). Zeitschrift für anorganische und allgemeine Chemie 641 (8–9): 1515–1520. doi:10.1002/zaac.201500201. https://onlinelibrary.wiley.com/doi/10.1002/zaac.201500201. 
  34. ↑ Musterle, Wilfried; Strähle, Joachim; Liebelt, Wolfgang; Dehnicke, Kurt (1979-07-01). "Darstellung, IR-Spektrum und Kristallstruktur von [WNCI 3 P0Cl 3 ] 4 2 POCI 3 / Preparation, IR Spectra and Crystal Structure of [WNCl 3 • P0Cl 3 ] 4 • 2 P0Cl 3" (in en). Zeitschrift für Naturforschung B 34 (7): 942–948. doi:10.1515/znb-1979-0713. ISSN 1865-7117. 
  35. ↑ Liese, Werner; Dehnicke, Kurt; Walker, Ingeborg; Strähle, Joachim (1979-05-01). "Darstellung, Eigenschaften und Kristallstruktur von Rhenium(VII)-Nitridchlorid, ReNCl 4 / Preparation, Properties and Crystal Structure of Rhenium(VII) Nitride Chloride, ReNCl 4" (in en). Zeitschrift für Naturforschung B 34 (5): 693–696. doi:10.1515/znb-1979-0509. ISSN 1865-7117. 
  36. ↑ 36.0 36.1 Binder, Anja; Maichle-Mössmer, Cäcilia; Niquet, Elke; Strähle, Joachim (July 2008). "Synthese und Kristallstruktur der Rhenium(VII)-Nitridchloride ReNCl4 und ReNCl4·H2O" (in de). Zeitschrift für anorganische und allgemeine Chemie 634 (8): 1326–1328. doi:10.1002/zaac.200800057. https://onlinelibrary.wiley.com/doi/10.1002/zaac.200800057. 
  37. ↑ Abram, Ulrich; Braun, Martin; Abram, Sonja; Kirmse, Reinhard; Voigt, Andreas (1998). "[NBu4[ReNCl4]: Facile synthesis, structure, electron paramagnetic resonance spectroscopy and reactions"]. Journal of the Chemical Society, Dalton Transactions (2): 231–238. doi:10.1039/a705881k. http://xlink.rsc.org/?DOI=a705881k. 
  38. ↑ "Kleinite Mineral Data". http://www.webmineral.com/data/Kleinite.shtml. 
  39. ↑ "Mosesite Mineral Data". http://www.webmineral.com/data/Mosesite.shtml. 
  40. ↑ Wang, Naizhou; Ye, Guojun; Hu, Guobing; Meng, Fanbao; Shang, Chao; Shi, Mengzhu; Ying, Jianjun; Chen, Xianhui (2019-08-05). "Absence of van der Waals Gap in Ternary Thorium Nitride ThNF and ThNCl" (in en). Inorganic Chemistry 58 (15): 9897–9903. doi:10.1021/acs.inorgchem.9b01050. ISSN 0020-1669. PMID 31291102. https://pubs.acs.org/doi/10.1021/acs.inorgchem.9b01050. 
  41. ↑ Nakamura, Akio; Akabori, Mitsuo; Ogawa, Toru; Huntelaar, M. (April 2005). "Uranium nitride chloride UNCl: 30K-class ferromagnet with layered structure" (in en). Physica B: Condensed Matter 359-361: 1021–1023. doi:10.1016/j.physb.2005.01.384. Bibcode: 2005PhyB..359.1021N. https://linkinghub.elsevier.com/retrieve/pii/S0921452605003893. 
Salts and covalent derivatives of the nitride ion
NH3 He(N2)11
Li3N Be3N2 BN β-C3N4
g-C3N4 		N2 NxOy NF3 Ne
Na3N Mg3N2 AlN Si3N4 PN
P3N5 		SxNy
SN
S4N4 		NCl3 Ar
K3N Ca3N2 ScN TiN VN CrN
Cr2N 		MnxNy FexNy CoN Ni3N CuN Zn3N2 GaN Ge3N4 As Se NBr3 Kr
Rb3N Sr3N2 YN ZrN NbN β-Mo2N Tc Ru Rh PdN Ag3N CdN InN Sn Sb Te NI3 Xe
Cs3N Ba3N2   Hf3N4 TaN WN Re Os Ir Pt Au Hg3N2 TlN Pb BiN Po At Rn
Fr3N Ra3N   Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
La CeN Pr Nd Pm Sm Eu GdN Tb Dy Ho Er Tm Yb Lu
Ac Th Pa UN Np Pu Am Cm Bk Cf Es Fm Md No Lr



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