Chemistry:Bromosyl trifluoride
From HandWiki
| Names | |
|---|---|
| Other names
Bromine oxide trifluoride, bromosyltrifluoride
| |
| Identifiers | |
3D model (JSmol)
|
|
PubChem CID
|
|
| |
| |
| Properties | |
| BrF3O | |
| Molar mass | 152.898 g·mol−1 |
| Appearance | colorless liquid |
| Related compounds | |
Related compounds
|
Chlorosyl trifluoride Iodosyl trifluoride |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Tracking categories (test):
Bromosyl trifluoride is an inorganic compound of bromine, fluorine, and oxygen with the chemical formula BrOF
3.[1][2]
Synthesis
Synthesis of bromosyl trifluoride is by reaction of anhydrous HF with K[BrOF
4] at –78 °C.[3]
- HF + K[BrOF
4] → BrOF
3 + K[HF
2]
- HF + K[BrOF
Physical properties
Bromosyl trifluoride forms a colorless liquid at room temperature. It reacts with water.[5]
Chemical properties
Bromosyl trifluoride is quite unstable and decomposes at room temperature:
- 2BrOF
3 → 2BrF
3 + O
2
- 2BrOF
References
- ↑ Gillespie, Ronald J.; Spekkens, Paul H. (1 January 1977). "Bromyl fluoride and bromosyl trifluoride: preparation and chemical and spectroscopic properties" (in en). Journal of the Chemical Society, Dalton Transactions (16): 1539–1546. doi:10.1039/DT9770001539. ISSN 1364-5447. https://pubs.rsc.org/en/Content/ArticleLanding/1977/DT/DT9770001539. Retrieved 24 May 2023.
- ↑ "bromine trifluoride oxide" (in en). ChemSrc. https://www.chemsrc.com/en/cas/61519-37-7_413747.html.
- ↑ Wiberg, Egon; Wiberg, Nils (2001) (in en). Inorganic Chemistry. Academic Press. p. 468. ISBN 978-0-12-352651-9. https://books.google.com/books?id=Mtth5g59dEIC&dq=Iodosyl+trifluoride&pg=PA468. Retrieved 24 May 2023.
- ↑ Ellern, Arkady; Boatz, Jerry A.; Christe, Karl O.; Drews, Thomas; Seppelt, Konrad (September 2002). "The Crystal Structures of ClF3O, BrF3O, and [NO]+[BrF4O]−" (in de). Zeitschrift für Anorganische und Allgemeine Chemie 628 (9–10): 1991–1999. doi:10.1002/1521-3749(200209)628:9/10<1991::AID-ZAAC1991>3.0.CO;2-1. ISSN 0044-2313.
- ↑ Haynes, William M. (9 June 2015) (in en). CRC Handbook of Chemistry and Physics, 96th Edition. CRC Press. p. 4-53. ISBN 978-1-4822-6097-7. https://books.google.com/books?id=RpLYCQAAQBAJ&dq=%22Bromosyl+trifluoride%22&pg=SA4-PA53. Retrieved 24 May 2023.
 |  |
