Chemistry:Borate chloride
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The borate chlorides are chemical compounds that contain both borate ions and chloride ions. They are mixed anion compounds. Many of them are minerals. Those minerals that crystallise with water (hydrates) may be found in evaporite deposits formed when mineral water has dried out.
List
| Chemical formula | Molar mass (g/mol) | Crystal system | Space group | Unit cell (Å) | Volume (Å3) | Density (g/cm3) | Comment | References | |
|---|---|---|---|---|---|---|---|---|---|
| Teepleite | Na 2[B(OH) 4]Cl |
tetragonal | P4/nmm | a = 7.25, c = 4.84 | 254.4 | 2.076 | Colourless, white or light beige crystals, with a vitreous, greasy, or dull lustre.
Uniaxial (-) nω = 1.519 nε = 1.503 Max birefringence δ = 0.016 |
[1] | |
| Boracite | Mg 3(B 7O 13)Cl |
orthorhombic | Pca21 | a = 8.577, b = 8.553, c = 12.09 Z=4 | 992.5 | 2.95 | Green, dark green (ferroan), blue, colourless, grey or white crystals with an adamantine, vitreous lustre if transparent.
Biaxial (+) nα = 1.658 - 1.662 nβ = 1.662 - 1.667 nγ = 1.668 - 1.673 2V 82° Max birefringence δ = 0.010 - 0.011 |
[2] | |
| Karlite | Mg 7(BO 3) 3(OH,Cl) 5 |
orthorhombic | a = 17.92, b = 17.6, c = 3.1 | 978 | 2.80 | White to light green crystals with a silky lustre.
Biaxial (-) nα = 1.589 nβ = 1.632 nγ = 1.634 2V 24° Max birefringence δ = 0.045 |
[3] | ||
| Shabynite | Mg 5(BO 3)(OH) 5(Cl,OH) 2 · 4H2O |
monoclinic | 2.32 | Colourless or white crystals with a silky lustre.
Biaxial (-) nα = 1.543 nβ = 1.571 nγ = 1.577 2V 49° Max birefringence δ = 0.034 |
[4] | ||||
| Satimolite | KNa 2Mg 2Al 5[B 12O 18(OH) 12](OH) 6Cl 4 · 4H2O |
trigonal | R3m | a = 15.1431, c = 14.456 Z=3 | 2.1 | White to colorless crystals with a vitreous or dull lustre.
Biaxial (-) nα = 1.535 nβ = 1.552 nγ = 1.553 2V 26° Max birefringence δ = 0.018 |
[5][6] | ||
| Kalborsite | K 6Al 4BSi 6O 20(OH) 4Cl |
Tetragonal | a = 9.85, c = 13.06 | 1,267 | 2.5 | Colorless with a slight rose-brownish tint crystals with a vitreous or pearly lustre.
Uniaxial (+) nω = 1.525 nε = 1.525 ? Max birefringence δ = 0.000 |
[7] | ||
| Hilgardite | Ca 2B 5O 9Cl · H2O |
triclinic | P1 | a=6.463 b=6.564 c=6.302 α = 61°38', β = 118°46', γ = 105°47' Z=1 | 205.8 | 2.67 to 2.71 | Colorless, light pink crystals with a vitreous lustre. | [8] | |
| Solongoite | Ca 2(H 3B 3O 7)(OH)Cl |
monoclinic | a = 7.93, b = 7.26, c = 12.54 β = 94° | 720 | 2.514 | Colourless crystals with a vitreous lustre.
Biaxial (+) nα = 1.510 nβ = 1.510 nγ = 1.545 Max birefringence δ = 0.035 |
[9] | ||
| Ekaterinite | Ca 2(B 4O 7)(Cl,OH) 2 · 2H2O |
hexagonal | a = 11.86, c = 23.88 | 2,909 | 2.440 | White or white with slight rose tint crystals with a pearly lustre.
Uniaxial (-) nω = 1.577 nε = 1.574 Max birefringence δ = 0.003 |
[10] | ||
| Chelkarite | CaMgB 2O 4(Cl,OH) 2 · 5H2O or near Cl:OH = 3:1 |
orthorhombic | a = 13.69, b = 20.84, c = 8.26 | 2,357 | 2.21 | Colorless crystals.
Biaxial (+) nα = 1.520 nγ = 1.558 Max birefringence δ = 0.038 |
[11] | ||
| Sakhaite | Ca 48Mg 16(BO 3) 32(CO 3) 16 · 2(H 2O,HCl) |
isometric | Fd3_m | a = 14.685 Z=4 | 3166.8 | 2.78 - 2.83 | Colourless, gray to grayish white crystals with a greasy lustre. | [12] | |
| Hydrochlorborite | Ca 4B 8O 15Cl 2 · 21H2O |
monoclinic | a = 22.78, b = 8.74, c = 17.06 β = 96.7° | 3373 | 1.83 - 1.85 | Colorless crystals with a vitreous, dull lustre.
Biaxial (+) nα = 1.499 nβ = 1.502 nγ = 1.521 2V 45° Max birefringence δ = 0.022 |
[13] | ||
| Heidornite | Na 2Ca 3B 5O 8(OH) 2(SO 4) 2Cl |
monoclinic | C2/c | a = 10.19, b = 7.76, c = 18.81
β = 93.33° Z=4 |
1,485 | 2.753 | Colorless crystals with a vitreous lustre.
Biaxial (+) nα = 1.579 nβ = 1.588 nγ = 1.604 2V 63° to 77° Max birefringence δ = 0.025 |
[14] | |
| Volkovskite | KCa 4[B 5O 8OH] 4[B(OH) 3] 2Cl · 4H2O |
triclinic | P1 | a = 6.57, b = 23.92, c = 6.52
α = 90.58°, β = 119.1°, γ = 95.56° |
889.2 | 2.27 | Colourless or pink; varying from pale to deep orange crystals with a vitreous lustre.
Biaxial (+) nα = 1.523 - 1.539 nβ = 1.539 - 1.540 nγ = 1.596 - 1.605 2V 14.6° Max birefringence δ = 0.073 |
[15] | |
| Kurgantaite | CaSr[B 5O 9]Cl · H2O |
triclinic | P1 | a = 6.5732, b = 6.4445, c = 6.3693, α = 60.995°, β = 61.257°, γ = 77.191° Z=1 | 2.99 | Colourless to white crystals with a vitreous lustre. | [16] | ||
| Chambersite | (Mn2+) 3(B 7O 13)Cl |
orthorhombic | Pca21 | a = 8.68, b = 8.68, c = 12.26 Z=4 | 924 | 3.49 | Colorless to deep purple crystals with a vitreous lustre.
Biaxial (+) nα = 1.732 nβ = 1.737 nγ = 1.744 2V 83° Max birefringence δ = 0.012 |
[17] | |
| Ericaite | (Fe2+) 3(B 7O 13)Cl |
orthorhombic | a = 8.58, b = 8.65, c = 12.17 | 903 | 3.17 - 3.27 | Red, green, purple, brown or black crystals.
Biaxial (-) nα = 1.731 nβ = 1.755 nγ = 1.755 Max birefringence δ = 0.024 |
[18] | ||
| Congolite | (Fe2+,Mg) 3[B 7O 13]Cl |
trigonal | R3c | a = 8.62, c = 21.05 | 1355 | 3.58 | Pale red or pink crystals.
Uniaxial (-) nω = 1.755 nε = 1.731 Max birefringence δ = 0.024 |
[19] | |
| Trembathite | (Mg,Fe2+) 3[B 7O 13]Cl |
trigonal | a = 8.57, c = 20.99 | 1335 | 2.84 - 3.34 | Colourless to pale blue transparent crystals with a vitreous lustre.
Uniaxial (-) nω = 1.684 nε = 1.668 Max birefringence δ = 0.016 |
[20][21] | ||
| Bandylite | Cu2+[B(OH) 4]Cl |
tetragonal | P4/nmm | a = 6.19 Å, c = 5.61 Z=2 | 214.9 | 2.81 | Deep blue crystals with greenish portions; cendre blue to Italian blue, becoming greener with atacamite inclusions, with a vitreous or pearly lustre.
Uniaxial (-) nω = 1.691 - 1.692 nε = 1.640 - 1.641 Max birefringence δ = 0.051 |
[22] | |
| Li 3B 8O 13Cl |
350.75 | Otrhorhombic | Pca21 | a=17.229 b=9.3827 c=6.6452 Z=4 | 1074.25 | 2.169 | birefringence 0.094 at 1064 nm | [23] | |
| Na4[B6O9(OH)3](H2O)Cl | Otrhorhombic | Pca21 | a=15.4867 b=8.6867 c=8.8551 Z=2 | 1191.3 | 2.260 | SHG 0.4 × KDP | [24] | ||
| Mg 3B 7O 13Cl[clarification needed] |
392.05 | orthorhombic | Pca21 | a=8.5319 b=8.5282 c=12.0730 Z=4 | 878.45 | 2.964 | NLO | [25] | |
| Sn 3B 10O 17Cl 2 |
orthorhombic | Pbcn | a =19.1905 b=10.3893 c=8.5164 | UV cutoff 280 nm; birefringence 0.125 at 546 nm | [26] | ||||
| Ba 6BO 3Cl 9 |
1201.90 | monoclinic | P21/n | a=8.229 b=12.259 c=19.080 β=90.20 Z=4 | 1924.7 | 4.418 | colourless | [27] | |
| NaBa 4Al 2B 8O 18Cl 3 |
tetragonal | P42nm | a = 12.048, c = 6.817 | NLO | [28] | ||||
| NaBa 4(GaB 4O 9) 2Cl 3 |
1192.62 | tetragonal | P42nm | a=12.1033 c=6.8329 Z=2 | 1001.0 | 3.957 | SHG 1.5xKDP | [29] | |
| Rb4Ba2.5B20O34Cl | 1481.10 | triclinic | P1 | a=6.756 b=11.086 c=11.288 α=99.07° β=90.60° γ=100.38° Z=1 | 820.6 | 2.9965 | colourless | [30] | |
| La(BO 2) 2Cl |
triclinic | [31] | |||||||
| Cs2La2B10O17Cl4 | 1065.54 | monoclinic | Cm | a=8.6904 b=20.92 c=6.4231 β =104.003 Z=2 | 1126.15 | 3.142 | SHG 2.1xKDP | [32] | |
| Ce(BO 2) 2Cl |
triclinic | P1 | a = 4.2174; b = 6.5763; c = 8.1221 α = 82, 152; β = 89, 206; γ = 72.048°; Z = 2 | [31] | |||||
| Ce 3[BO 3] 2Cl 3 |
hexagonal | P63/m | a = 9.2008, c = 5.8079; Z = 2 | [31] | |||||
| Pr(BO 2) 2Cl |
triclinic | [31] | |||||||
| Sm 4[B 16O 26(OH) 4(H 2O) 3Cl 4] |
[33] | ||||||||
| Eu 4[B 16O 26(OH) 4(H 2O) 3Cl 4] |
[33] | ||||||||
| Gd 4[B 16O 26(OH) 4(H 2O) 3Cl 4] |
[33] | ||||||||
| Pb 6BO 4Cl 7 |
1566 | triclinic | P1_ | a=8.001 b=8.054 c=13.116 α=89.52 β=89.66 γ=69.942 | 793.9 | 6.551 | colourless | [27] | |
| Pu 4[B 16O 26(OH) 4(H 2O) 3Cl 4] |
[34] | ||||||||
| Am 4[B 16O 26(OH) 4(H 2O) 3Cl 4] |
[34] | ||||||||
| Cm 4[B 16O 26(OH) 4(H 2O) 3Cl 4] |
[34] | ||||||||
| Cf 4[B 16O 26(OH) 4(H 2O) 3Cl 4] |
[34] |
References
- ↑ "Teepleite". https://www.mindat.org/min-3901.html.
- ↑ "Boracite". https://www.mindat.org/min-721.html.
- ↑ "Karlite". https://www.mindat.org/min-2160.html.
- ↑ "Shabynite". https://www.mindat.org/min-3627.html.
- ↑ "Satimolite". https://www.mindat.org/min-3541.html.
- ↑ "Satimolite Mineral Data". http://webmineral.com/data/Satimolite.shtml#.ZBx1lnbMLIU.
- ↑ "Kalborsite". https://www.mindat.org/min-2135.html.
- ↑ Rumanova, I. M.; Iorysh, Z. I.; Belov, N. V. (1977). "Crystal structure of triclinic hilgardite Ca2[B5O9Cl⋅H2O=Ca2[Bt3BΔ2O9]Cl⋅H2O"]. Dokl. Akad. Nauk SSSR 23 (1): 91–94. http://www.mathnet.ru/php/archive.phtml?wshow=paper&jrnid=dan&paperid=41212&option_lang=eng. Retrieved 2020-12-10.
- ↑ "Solongoite". https://www.mindat.org/min-3710.html.
- ↑ "Ekaterinite". https://www.mindat.org/min-1362.html.
- ↑ "Chelkarite". https://www.mindat.org/min-985.html.
- ↑ "Sakhaite". https://www.mindat.org/min-3504.html.
- ↑ "Hydrochlorborite". https://www.mindat.org/min-1970.html.
- ↑ "Heidornite". https://www.mindat.org/min-1846.html.
- ↑ "Volkovskite". https://www.mindat.org/min-4202.html.
- ↑ "Kurgantaite". https://www.mindat.org/min-8212.html.
- ↑ "Chambersite". https://www.mindat.org/min-966.html.
- ↑ "Ericaite". https://www.mindat.org/min-1396.html.
- ↑ "Congolite". https://www.mindat.org/min-1118.html.
- ↑ "Trembathite". https://www.mindat.org/min-4010.html.
- ↑ "Trembathite Mineral Data". http://webmineral.com/data/Trembathite.shtml#.ZBzK3nbMLIV.
- ↑ "Bandylite". https://www.mindat.org/min-506.html.
- ↑ Hu, Mei; Tuerhong, Nuerbiye; Chen, Zhaohui; Jing, Qun; Lee, Ming-Hsien (16 February 2023). "Li 3 B 8 O 13 X (X = Cl and Br): Two New Noncentrosymmetric Crystals with Large Birefringence Induced by BO 3 Units". Inorganic Chemistry 62 (8): 3609–3615. doi:10.1021/acs.inorgchem.2c04376. PMID 36795025.
- ↑ Tang, Ru-Ling; Huai, Lei; Liu, Wenlong (2023-06-12). "Na 4 [B 6 O 9 (OH) 3 (H 2 O) Cl: A Deep-Ultraviolet Transparent Nonlinear Optical Borate Chloride with {[B 6 O 9 (OH) 3 ] 3– } ∞ Chains"] (in en). Inorganic Chemistry 62 (25): 9759–9764. doi:10.1021/acs.inorgchem.3c01443. ISSN 0020-1669. PMID 37307417. https://pubs.acs.org/doi/10.1021/acs.inorgchem.3c01443.
- ↑ Wang, Zujian; Qiao, Huimin; Su, Rongbing; Hu, Bing; Yang, Xiaoming; He, Chao; Long, Xifa (October 2018). "Mg 3 B 7 O 13 Cl: A New Quasi-Phase Matching Crystal in the Deep-Ultraviolet Region" (in en). Advanced Functional Materials 28 (41): 1804089. doi:10.1002/adfm.201804089. http://doi.wiley.com/10.1002/adfm.201804089.
- ↑ Deng, Lihan; Wu, Mengfan; Yang, Zhihua; Han, Shujuan; Pan, Shilie (2022-11-01). "Sn 3 B 10 O 17 Cl 2 Achieving Birefringence Enhancement by Stereochemical Activity Lone Pair" (in en). Inorganic Chemistry 61 (45): 18238–18244. doi:10.1021/acs.inorgchem.2c03068. ISSN 0020-1669. PMID 36318717. https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c03068.
- ↑ 27.0 27.1 Li, Wei; Wu, Hongping; Yu, Hongwei; Hu, Zhanggui; Wang, Jiyang; Wu, Yicheng (2020). "Ba 6 BO 3 Cl 9 and Pb 6 BO 4 Cl 7 : structural insights into ortho -borates with uncondensed BO 4 tetrahedra" (in en). Chemical Communications 56 (45): 6086–6089. doi:10.1039/D0CC01927E. ISSN 1359-7345. PMID 32352464. http://xlink.rsc.org/?DOI=D0CC01927E.
- ↑ Zhang, Jianxiu; Zhang, Shufeng; Wu, Yicheng; Wang, Jiyang (2012-06-18). "New Nonlinear Optical Crystal: NaBa 4 Al 2 B 8 O 18 Cl 3" (in en). Inorganic Chemistry 51 (12): 6682–6686. doi:10.1021/ic300306v. ISSN 0020-1669. PMID 22663174. https://pubs.acs.org/doi/10.1021/ic300306v.
- ↑ Wen, Ming; Su, Xin; Wu, Hongping; Lu, Juanjuan; Yang, Zhihua; Pan, Shilie (2016-03-24). "NaBa 4 (GaB 4 O 9 ) 2 X 3 (X = Cl, Br) with NLO-Active GaO 4 Tetrahedral Unit: Experimental and ab Initio Studies" (in en). The Journal of Physical Chemistry C 120 (11): 6190–6197. doi:10.1021/acs.jpcc.6b00265. ISSN 1932-7447. https://pubs.acs.org/doi/10.1021/acs.jpcc.6b00265.
- ↑ Mutailipu, Miriding; Zhang, Min; Dong, Xiaoyu; Chen, Yanna; Pan, Shilie (2016-10-17). "Effects of the Orientation of [B 5 O 11 7– Fundamental Building Blocks on Layered Structures Based on the Pentaborates"] (in en). Inorganic Chemistry 55 (20): 10608–10616. doi:10.1021/acs.inorgchem.6b01855. ISSN 0020-1669. PMID 27669101. https://pubs.acs.org/doi/10.1021/acs.inorgchem.6b01855.
- ↑ 31.0 31.1 31.2 31.3 Nikelski, Tanja; Schleid, Thomas (January 2003). "Zwei Cer(III)-Chlorid-Oxoborate im Vergleich: Ce3Cl3[BO32 und CeCl(BO2)2"] (in de). Zeitschrift für anorganische und allgemeine Chemie 629 (1213): 2200–2205. doi:10.1002/zaac.200300208. ISSN 0044-2313. http://doi.wiley.com/10.1002/zaac.200300208.
- ↑ Shi, Xuping; Tudi, Abudukadi; Gai, Minqiang; Yang, Zhihua; Han, Shujuan; Pan, Shilie (2023-07-06). "Ultraviolet Crystal with Strong Optical Nonlinearity by Creating Halogen-Centered Secondary Building Blocks" (in en). Chemistry of Materials 35 (14): 5680–5688. doi:10.1021/acs.chemmater.3c01246. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/acs.chemmater.3c01246.
- ↑ 33.0 33.1 33.2 Stritzinger, Jared Tyler (2015) (in en). Synthetic Exploration of F-Element Borates and Plumbites. https://fsu.digital.flvc.org/islandora/object/fsu%3A253045/.
- ↑ 34.0 34.1 34.2 34.3 Stritzinger, Jared Tyler (2015) (in en). Synthetic Exploration of F-Element Borates and Plumbites. https://fsu.digital.flvc.org/islandora/object/fsu%3A253045/.
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