Chemistry:Wavellite

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Short description: Aluminium phosphate basic hydrate mineral
Wavellite
Wavellite-162460.jpg
Wavellite cluster from Mauldin Mountain Quarries, Mauldin Mt., Montgomery County, Arkansas
General
CategoryPhosphate minerals
Formula
(repeating unit)
Al3(PO4)2(OH,F)3·5H2O
Strunz classification8.DC.50
Crystal systemOrthorhombic
Crystal classDipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)
Space groupPcmn
Unit cella = 9.621 Å
b = 17.363 Å,
c = 6.994 Å; Z = 4
Identification
ColorGreen to yellowish-green and greenish blue and blue. and yellow, brown, white and colorless
Crystal habitSpherical, radial aggregates; striated prisms; crusty to stalactitic
Cleavage[110] perfect, [101] good, [010] distinct
FractureUneven to subconchoidal
Mohs scale hardness3.5 - 4
|re|er}}Vitreous to resinous, pearly
StreakWhite
DiaphaneityTranslucent
Specific gravity2.36
Optical propertiesBiaxial (+)
Refractive indexnα = 1.518 - 1.535 nβ = 1.524 - 1.543 nγ = 1.544 - 1.561
Birefringenceδ = 0.026
PleochroismWeak; X = greenish; Z = yellowish
2V angleMeasured: 60° to 72°
FusibilityInfusable, swells and splits on heating
SolubilityInsoluble
References[1][2][3][4]

Wavellite is an aluminium basic phosphate mineral with formula Al3(PO4)2(OH, F)3·5H2O. Distinct crystals are rare, and it normally occurs as translucent green radial or spherical clusters.[6]

Discovery and occurrence

Wavellite from the Avant Mine, Garland County, Arkansas, showing spherical structure (size: 3.4 x 2.0 x 1.1 cm)

Wavellite was first described in 1805 for an occurrence at High Down, Filleigh, Devon, England and named by William Babington in 1805 in honor of Dr. William Wavell (1750–1829),[3] a Devon-based physician, botanist, historian, and naturalist, who brought the mineral to the attention of fellow mineralogists.[7][3][6][8]

It occurs in association with crandallite and variscite in fractures in aluminous metamorphic rock, in hydrothermal regions and in phosphate rock deposits.[1] It is found in a wide variety of locations notably in the Mount Ida, Arkansas area in the Ouachita Mountains.

It is sometimes used as a gemstone.[9]

See also

References

  1. 1.0 1.1 Handbook of Mineralogy
  2. Webmineral
  3. 3.0 3.1 3.2 Mindat
  4. Klein, Corneis and Cornelius S. Hurlbut, Jr., Manual of Mineralogy, Wiley, 20th ed. 1985, p. 362-3 ISBN:0-471-80580-7
  5. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode2021MinM...85..291W. 
  6. 6.0 6.1 Chisholm, Hugh, ed (1911). "Wavellite". Encyclopædia Britannica. 28 (11th ed.). Cambridge University Press. p. 430. 
  7. Green, David; Cotterell, Tom; Jones, I.; Cox, D.; Cleevely, R. (2007). "Wavellite: its discovery and occurrences in the British Isles.". UK Journal of Mines and Minerals 28: 11–30. 
  8. Curtis, Samuel and Hooker, William Jackson (1827). Memoirs of the Life and Writing of the Late Mr. William Curtis, Curtis's Botanical Magazine; or Flower Garden Displayed, v. 1 (new series), v-xxxii.
  9. Gemstones: Properties, identification and use by Arthur Thomas, p. 132.

External links