Chemistry:Telluride oxide

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Short description: Class of chemical compounds

The telluride oxides or oxytellurides are double salts that contain both telluride and oxide anions (Te2− and O2−). They are in the class of mixed anion compounds.

Compounds that can be mistakenly called "telluride oxides" are tellurium dioxide and tellurite.

Some of these are under investigation as photovoltaic materials, e.g. oxygen doped zinc telluride.[1]

Structure

Due to the different size and chemical nature of Te2− and O2− the ions occupy different positions in the crystal structure. Some of these structures are layered.[2]

Many of the crystal systems are tetragonal. One unusual structure has stacked tubes made from tellurium, with nested tubes of antimony oxide, which contain alkali metal.[3]

List

name formula MW ratio

Te:O

system space group unit cell

Å

volume density optical band gap CAS references
V2Te2O 2:1 tetragonal a = 3.9282 and c = 13.277 [4]
KV3Te3O0.42 hexagonal P63/m a=9.62, c=4.48 359 [5]
Rb0.8V2Te2O 2:1 [6]
Sr2MnO2Cu1.82Te2 I4/mmm a=4.200933 c=19.28303 340.304 [2]
Sr2CoO2Cu2Te2 I4/mmm a=4.152337 c=19.54645 337.018 [2]
oxygen doped zinc telluride ZnTe1−xOx
Ga2O2.95Te0.05 [7]
Tetragadolinium bis[tetraoxidosilicate(IV)] oxide telluride Gd4(SiO4)2OTe 956.78 orthorhombic Pnma a=12.495 b=10.8683 c=6.8075 Z=4 924.5 6.874 colourless [8]
Niobium iodide oxide telluride Nb4I4Te9O
Antimony copper oxide telluride CuSbTeO
dibarium cobalt disilver dioxide ditelluride Ba2CoO2Ag2Te2 836.52 2:2 tetragonal I4/mmm [9]
Be3Cd4Ge3O12Te 12449-27-3
SBC-1 (K6(H2O)6Sb12O18)3Te36 tellurium tubes [3][10]
RB-CTH-1 Rb18Sb36O54(SbTe3)2(Te2)6 tellurium tubes [11][12]
Ba2TeO 1:1 tetragonal P4/nmm a=5.0337, c=9.9437, Z=2 semiconductor 2.93 [13]
LaCuOTe 1:1 tetragonal P4/nmm a = 4.1775, c = 9.326 162.75 2.31 [14]
CeCuOTe 1:1 tetragonal P4/nmm a = 4.1497, c = 9.309 160.30 [14]
La2O2Te 1:2 tetragonal I4/mmm a=4.1231 c=13.096 Z=2 6.525 [15]
Ce2O2Te 1:2 tetragonal I4/mmm a=4.0817 c=12.947 Z=2 6.772 [15]
CeOCuTe 7.39
Pr2O2Te 1:2 I4/mmm a=4.0562 c=12.858 211.5 6.930 [15]
PrOCuTe 7.32
NdCuOTe 1:1 tetragonal P4/nmm a = 4.1056, c = 9.332 157.30 2.26 [14]
Nd2O2Te 1:2 tetragonal I4/mmm a=4.0308 c=12.771 7.172 [15]
samarium(III) oxide telluride Sm2TeO2 1:2 tetragonal I4/mmm a=3.9983 c=12.655 7.556 [16][15]
Eu2TeO2 1:2 tetragonal I4/mmm a=3.9756 c=12.579 Z=2 7.743 [15]
Gd2TeO2 1:2 tetragonal I4/mmm a=3.9620 c=12.532 Z=2 8.004 [15]
Tb2TeO2 1:2 tetragonal I4/mmm a=3.9389 c=12.454 Z=2 8.206 89800-88-4 [15]
Dy2TeO2 1:2 tetragonal I4/mmm a=3.9234 c=12.403 Z=2 8.430 [15]
Ho2TeO2 orthorhombic Cmc21 a=3.8505 b=12.9004 c=4.0521 Z=2 8.075 [15]
Er2TeO2 orthorhombic Cmc21 a=3.8263 b=12.8297 c=4.0240 Z=2 8.307 [15]
BiOCuTe 1:1 tetragonal P4/nmm a=4.04200 c=9.5234 [17]
Bi2O2Te 1:2 tetragonal I4/mmm a=3.98025 c=12.7039 semiconductor 0.23 [18]
thorium oxytelluride ThOTe 375.64 1:1 tetragonal P4/nmm a=4.1173 c=7.5289 Z=2 127.63 9.775 black 1.45 [19]
UOTe 1:1 tetragonal P4/nmm a=4.004 c=7.491 [20][21]
U4O4Te3 3:4 tetragonal I4/mmm a=4.010 c=27.54 Z=2 [20]
U2O2Te 1:2 [20]
neptunium oxide telluride Np2TeO2 1:2 Tetragonal I4/mmm a=4.003 c=12.73 Z=2 [22]
Pu2TeO2 1:2 tetragonal I4/mmm a = 4.008, c = 12.659 Z=2 203.4 10.58 0.65 [23]
Am2TeO2 tetragonal I4/mmm a=3.994 c=12.72
Cm2TeO2 I4/mmm a=3.98 c=12.58 [24]

References

  1. ↑ Tanaka, Tooru; Saito, Katsuhiko; Guo, Qixin; Yu, Kin Man; Walukiewicz, Wladek (2020-03-05). "Intermediate band solar cells based on highly mismatched II-VI oxide semiconductors". in Teherani, Ferechteh H.; Look, David C.; Rogers, David J.. Oxide-based Materials and Devices XI. 11281. San Francisco, United States: SPIE. pp. 60. doi:10.1117/12.2550950. ISBN 978-1-5106-3325-4. Bibcode: 2020SPIE11281E..1UT. 
  2. ↑ 2.0 2.1 2.2 Blandy, Jack N.; Parker, Dinah R.; Cassidy, Simon J.; Woodruff, Daniel N.; Xu, Xiaoyu; Clarke, Simon J. (2019-06-17). "Synthesis, Structure, and Compositional Tuning of the Layered Oxide Tellurides Sr 2 MnO 2 Cu 2– x Te 2 and Sr 2 CoO 2 Cu 2 Te 2" (in en). Inorganic Chemistry 58 (12): 8140–8150. doi:10.1021/acs.inorgchem.9b00919. ISSN 0020-1669. PMID 31185546. 
  3. ↑ 3.0 3.1 Palmqvist, Anders E. C.; Iversen, Bo B.; Zanghellini, Ezio; Behm, Mårten; Stucky, Galen D. (2004-01-30). "A Crystalline Microporous Narrow-Bandgap Semiconductor" (in en). Angewandte Chemie International Edition 43 (6): 700–704. doi:10.1002/anie.200351284. ISSN 1433-7851. PMID 14755696. 
  4. ↑ Ablimit, Abduweli; Sun, Yun-Lei; Cheng, Er-Jian; Liu, Ya-Bin; Wu, Si-Qi; Jiang, Hao; Ren, Zhi; Li, Shiyan et al. (2018-12-03). "V 2 Te 2 O: A Two-Dimensional van der Waals Correlated Metal" (in en). Inorganic Chemistry 57 (23): 14617–14623. doi:10.1021/acs.inorgchem.8b02280. ISSN 0020-1669. PMID 30450892. 
  5. ↑ Wu, Eric J.; Pell, Michael A.; Genin, Hugh S.; Ibers, James A. (August 1998). "Synthesis, characterization, and electronic structure of KV3Te3O0.42" (in en). Journal of Alloys and Compounds 278 (1–2): 123–129. doi:10.1016/S0925-8388(98)00585-4. 
  6. ↑ Ablimit, Abduweli; Sun, Yun-Lei; Jiang, Hao; Wu, Si-Qi; Liu, Ya-Bin; Cao, Guang-Han (2018-06-20). "Weak metal-metal transition in the vanadium oxytelluride Rb 1 − δ V 2 Te 2 O" (in en). Physical Review B 97 (21): 214517. doi:10.1103/PhysRevB.97.214517. ISSN 2469-9950. 
  7. ↑ Kim, J. S.; Lee, S. B.; Bahng, J. H.; Choi, J. C.; Park, H. L.; Mho, S. I.; Kim, T. W.; Whang, Y. H. et al. (2001). "Optical Characteristics of Emission from β-Ga2O3 with Group-VIb Ions" (in en). Physica Status Solidi A 187 (2): 569–573. doi:10.1002/1521-396X(200110)187:2<569::AID-PSSA569>3.0.CO;2-R. ISSN 1521-396X. 
  8. ↑ Daszkiewicz, Marek; Gulay, Lubomir D. (2015-07-01). "Accidental formation of Gd 4 (SiO 4 ) 2 OTe: crystal structure and spectroscopic properties". Acta Crystallographica Section C 71 (7): 598–601. doi:10.1107/S2053229615011651. ISSN 2053-2296. PMID 26146399. http://scripts.iucr.org/cgi-bin/paper?S2053229615011651. 
  9. ↑ Matsumoto, Yuki; Nambu, Yusuke; Honda, Takashi; Ikeda, Kazutaka; Otomo, Toshiya; Kageyama, Hiroshi (21 May 2020). "High-pressure Synthesis of Ba2CoO2Ag2Te2 with Extended CoO2 Planes". Inorganic Chemistry 59 (12): 8121–8126. doi:10.1021/acs.inorgchem.0c00429. PMID 32437136. 
  10. ↑ Liebau, F. (May 2004). "Microporous materials of the nth-order: new classes of poroates" (in en). Microporous and Mesoporous Materials 70 (1–3): 103–108. doi:10.1016/j.micromeso.2004.02.006. 
  11. ↑ Shulman, Alexander; Palmqvist, Anders E. C. (2007-01-22). "A Crystalline, Large-Pore, Microporous Semiconductor" (in de). Angewandte Chemie 119 (5): 732–736. doi:10.1002/ange.200603075. PMID 17154204. Bibcode: 2007AngCh.119..732S. 
  12. ↑ Shulman, Alexander; Zanghellini, Ezio; Palmqvist, Anders E.C. (September 2010). "Reversible sorption in the crystalline microporous semiconductor Rb-CTH-1" (in en). Journal of Solid State Chemistry 183 (9): 1912–1916. doi:10.1016/j.jssc.2010.06.012. Bibcode: 2010JSSCh.183.1912S. 
  13. ↑ Besara, T.; Ramirez, D.; Sun, J.; Whalen, J.B.; Tokumoto, T.D.; McGill, S.A.; Singh, D.J.; Siegrist, T. (February 2015). "Ba2TeO: A new layered oxytelluride" (in en). Journal of Solid State Chemistry 222: 60–65. doi:10.1016/j.jssc.2014.11.003. Bibcode: 2015JSSCh.222...60B. 
  14. ↑ 14.0 14.1 14.2 Liu, Min Ling; Wu, Li Bin; Huang, Fu Qiang; Chen, Li Dong; Ibers, James A. (January 2007). "Syntheses, crystal and electronic structure, and some optical and transport properties of LnCuOTe (Ln=La, Ce, Nd)" (in en). Journal of Solid State Chemistry 180 (1): 62–69. doi:10.1016/j.jssc.2006.09.014. Bibcode: 2007JSSCh.180...62L. 
  15. ↑ 15.00 15.01 15.02 15.03 15.04 15.05 15.06 15.07 15.08 15.09 15.10 Weber, Frank (1999). Präparative Studien in den Mehrstoffsystemen Selten-Erd-Metall - Selen bzw. Tellur und Sauerstoff (doctoralThesis) (in Deutsch). Universität Stuttgart, Universität Stuttgart. doi:10.18419/OPUS-668.
  16. ↑ Petzel, T.; Ludwigs, J. (February 1987). "The thermodynamics of vaporization and formation of samarium(III) oxide telluride" (in en). Journal of the Less Common Metals 128: 241–247. doi:10.1016/0022-5088(87)90211-6. 
  17. ↑ Vaqueiro, Paz; Guélou, Gabin; Stec, Maria; Guilmeau, Emmanuel; Powell, Anthony V. (2013). "A copper-containing oxytelluride as a promising thermoelectric material for waste heat recovery" (in en). J. Mater. Chem. A 1 (3): 520–523. doi:10.1039/C2TA00878E. ISSN 2050-7488. http://xlink.rsc.org/?DOI=C2TA00878E. 
  18. ↑ Luu, Son D.N.; Vaqueiro, Paz (March 2015). "Synthesis, characterisation and thermoelectric properties of the oxytelluride Bi2O2Te" (in en). Journal of Solid State Chemistry 226: 219–223. doi:10.1016/j.jssc.2015.02.026. Bibcode: 2015JSSCh.226..219L. http://centaur.reading.ac.uk/39759/1/revised%20manuscript.pdf. 
  19. ↑ Koscielski, Lukasz A.; Ringe, Emilie; Van Duyne, Richard P.; Ellis, Donald E.; Ibers, James A. (2012-08-06). "Single-Crystal Structures, Optical Absorptions, and Electronic Distributions of Thorium Oxychalcogenides ThOQ (Q = S, Se, Te)" (in en). Inorganic Chemistry 51 (15): 8112–8118. doi:10.1021/ic300510x. ISSN 0020-1669. PMID 22799890. 
  20. ↑ 20.0 20.1 20.2 Noël, H.; Potel, M.; Shlyk, L.; Kaczorowski, D.; Troć, R. (January 1995). "Synthesis and crystal structure of a novel uranium oxytelluride U4O4Te3" (in en). Journal of Alloys and Compounds 217 (1): 94–96. doi:10.1016/0925-8388(94)01301-W. 
  21. ↑ Klein Haneveld, A.J.; Jellinek, F. (June 1964). "Uranium oxide telluride" (in en). Journal of Inorganic and Nuclear Chemistry 26 (6): 1127–1128. doi:10.1016/0022-1902(64)80277-3. 
  22. ↑ Thévenin, T.; Jové, J.; Pagès, M. (September 1985). "Tetragonal neptunium oxide telluride Np2O2Te : Crystallographic and 237Np mössbauer studies" (in en). Materials Research Bulletin 20 (9): 1075–1080. doi:10.1016/0025-5408(85)90207-7. 
  23. ↑ Costantini, J.M.; Damien, D.; de Novion, C.H.; Blaise, A.; Cousson, A.; Abazli, H.; Pagès, M. (April 1983). "Crystal chemistry, magnetic, and electrical properties of the tetragonal plutonium oxide telluride Pu2O2Te" (in en). Journal of Solid State Chemistry 47 (2): 219–224. doi:10.1016/0022-4596(83)90010-5. Bibcode: 1983JSSCh..47..219C. 
  24. ↑ Morss, L. R.; Edelstein, Norman M.; Fuger, Jean (2010-10-21) (in en). The Chemistry of the Actinide and Transactinide Elements (Set Vol.1-6): Volumes 1-6. Springer Science & Business Media. pp. 1421. ISBN 978-94-007-0211-0. https://books.google.com/books?id=9vPuV3A0UGUC&pg=PA1421. 



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