Chemistry:Strashimirite

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Strashimirite
Strashimirite-88588.jpg
General
CategoryArsenate mineral
Formula
(repeating unit)
Cu
8
(AsO
4
)
4
(OH)
4
 · 5(H
2
O)
Strunz classification8.DC.12 (10 ed)
7/D.07-20 (8 ed)
Dana classification42.6.5.1
Crystal systemMonoclinic
Unknown space group
Space groupP2/m, P2, or Pm
Unit cella = 9.71 Å, b = 18.81 Å
c = 8.94 Å; β = 97.2°; Z = 3
Identification
ColorWhite, pale green
Crystal habitElongated, tabular crystals; crusts; radiating aggregates
CleavageParting at right angle to elongation
Mohs scale hardness2.5–3
|re|er}}Greasy, pearly
DiaphaneitySemitransparent
Specific gravity3.67 (calculated)
Optical propertiesBiaxial (−)
Refractive indexnα = 1.726 nγ = 1.747
Birefringenceδ = 0.021
PleochroismWeak; Y = very pale yellowish green; Z = yellowish green
2V angle70°
References[1][2][3][4][5]

Strashimirite (IMA symbol: Ssh[7]) is a rare monoclinic mineral containing arsenic, copper, hydrogen, and oxygen. It has the chemical formula Cu
8
(AsO
4
)
4
(OH)
4
 · 5(H
2
O)
.[8][9]

This mineral was discovered in Zapachitsa (Zapacica) copper deposit, Svoge, Sofia Oblast, Bulgaria in 1960, by Bulgarian mineralogist Jordanka Minčeva-Stefanova. She named it after Strashimir Dimitrov (1892–1960), Professor in Mineralogy and Petrography at Sofia University "St Kliment Ohridski", Bulgaria.[10] The International Mineralogical Association approved it as a new mineral in 1968.[11]

It occurs as a secondary mineral phase in the oxidation zone of copper arsenide deposits. It occurs associated with tyrolite, cornwallite, clinoclase, euchroite, olivenite, parnauite, goudeyite, arthurite, metazeunerite, chalcophyllite, cyanotrichite, scorodite, pharmacosiderite, brochantite, azurite, malachite and chrysocolla.[1]

Although it remains quite rare, strashimirite has subsequently been identified in a number of locations including: Novoveska Huta in the Czech Republic; on the west flank of Cherbadung (Pizzo Cervandone), Binntal, Valais, Switzerland; in Kamsdorf and Saalfeld, Thuringia, Germany; the Clara mine, near Oberwolfach, Black Forest, Germany; in the Richelsdorf Mountains, Hesse, Germany; Cap Garonne mine, near le Pradet, Var, and Triembach-au-Val, Haut-Rhin, France; Wheals Gorland and Unity, Gwennap, Cornwall, England; the Tynagh mine, near Loughrea, Co. Galway, Ireland; the Majuba Hill mine, Antelope district, Pershing Co. Nevada, US; and the Centennial Eureka mine, Tintic district, Juab Co., Utah, US.[1]

See also

Notes

  1. 1.0 1.1 1.2 "Information page for Strashimirite". Handbook of Mineralogy. http://www.handbookofmineralogy.org/pdfs/strashimirite.pdf. 
  2. "Information page for Strashimirite". Mindat. http://www.mindat.org/min-3799.html. 
  3. "Information page for Strashimirite". Webmineral. http://webmineral.com/data/Strashimirite.shtml. 
  4. "Information about Strashimirite". RRUFF Database. http://rruff.info/Strashimirite. 
  5. "Strashimirite". Mineralienatlas Lexicon. http://www.mineralatlas.eu/lexikon/index.php/MineralData?mineral=Strashimirite. 
  6. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode2021MinM...85..291W. https://www.cambridge.org/core/journals/mineralogical-magazine/article/imacnmnc-approved-mineral-symbols/62311F45ED37831D78603C6E6B25EE0A. 
  7. Warr, L.N. (2021). "IMA-CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode2021MinM...85..291W. https://rruff.info/rruff_1.0/uploads/MM85_291.pdf. Retrieved 30 December 2021. 
  8. Mincheva-Stefanova, I. (1968). "Strashimirite - a new hydrous copper arsenate" (in ru). Zapiski RMO (Proceedings of the Russian Mineralogical Society) (97): 4. http://rruff.info/uploads/ZVMO97N4_470.pdf. 
  9. Frost, Ray L.; Keeffe, Eloise C.; Cejka, Jiri; Sejkora, Jiri (2009). "Vibrational spectroscopic study of the arsenate mineral strashimirite Cu8(AsO4)4(OH)4.5H2O - relationship to other basic copper arsenates". Vibrational Spectroscopy 50 (2): 289–297. doi:10.1016/j.vibspec.2009.02.002. http://eprints.qut.edu.au/20877/1/c20877.pdf. 
  10. Fleischer, Michael (1969). "New Mineral Names". The American Mineralogist 54: 1221. http://rruff.info/uploads/AM54_1218.pdf. 
  11. Stoilova, D.; Minčeva-Stefanova, J (2001). "Infrared Spectroscopic Study of Strashimirite". Comptes Rendus de l'Académie Bulgare des Sciences 54 (8): 49–52. http://articles.adsabs.harvard.edu/full/seri/CRABS/0054//H000049.000.html. 

External links