Chemistry:Selenite sulfate
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Selenite sulfates are mixed anion compounds containing both selenite (SeO3), and sulfate (SO4) anions. They have transparent crystals that may be coloured by cations. Selenite sulfate minerals are known including pauladamsite and munakataite.
List
| name | formula | ratio
SeO3:SO4 |
mw | system | space group | unit cell Å | volume | density | comments | references |
|---|---|---|---|---|---|---|---|---|---|---|
| Co3(SeO3)(SO4)(OH)2 | orthorhombic | Pnma | a 10.8757 b 6.4782 c 11.1579 | [1] | ||||||
| Pauladamsite | Cu4(SeO3)(SO4)(OH)4·2H2O | triclinic | P1 | a = 6.0742 b = 8.415 c = 10.780 α = 103.665 β = 95.224 γ = 90.004° Z = 2 | 533.0 | green | [2] | |||
| Cd4(SeO3)2(SO4)2 | orthorhombic | P212121 | a=5.3524 b=14.595 c=15.892 | [3] | ||||||
| Ag2Cd(Se2O5)(Se0.3S0.7O4) | triclinic | P1 | a 6.7485 b 6.8504 c 9.769, α 101.36° β 105.95° γ 91.16° | [4] | ||||||
| Pr2(SeO3)2(SO4)(H2O)2 | monoclinic | C2 | a=11.719 b=6.8495 c=6.5043 β=103.265 Z=2 | 508.18 | 4.364 | light green | [5] | |||
| Sm2(SeO3)2(SO4)(H2O)2 | monoclinic | C2 | [6] | |||||||
| Dy2(SeO3)2(SO4)(H2O)2 | monoclinic | C2 | [6] | |||||||
| Yb2(SeO3)2(SO4)(H2O)2 | monoclinic | C2 | [6] | |||||||
| Hf(SeO3)(SeO4)(H2O)4 | [7] | |||||||||
| Hg2(SeO3)(SO4) | monoclinic | P21/c | a 6.3799 b 7.0185 c 13.4426 β 94.511° | birefringence 0.133 at 532 nm and 0.126 at 1064 nm | [4] | |||||
| Hg3(SeO3)2(SO4) | monoclinic | P21 | a 8.1991 b 5.2677 c 11.1199 β 108.399(6)° | white; band gap (4.70 eV; SHG 1.3 ×KDP | [8] | |||||
| La2Hg3(SeO3)4(SO4)2(H2O)2 | triclinic | P1 | a 9.1127 b 9.2446 c 13.5562 α 86.099° β 79.267° γ 61.814° | [4] | ||||||
| munakataite | Pb2Cu2(Se4+O3)(SO4)(OH)4 | monoclinic | P21/m | a = 9.802 b = 5.675 c = 9.281 β = 102.443 Z = 2 | 504.2 | [9] |
References
- ↑ Zhang, Mengsi; Song, Yujie; Zhao, Zhiying; Li, Jinyang; Zhang, Wanwan; Xie, Yaxin; Huang, Xing; Huang, Xiaoying et al. (2020-06-15). "Co 3 (SeO 3 )(SO 4 )(OH) 2 : A Selenite-Sulfate Compound with a Distorted Kagomé Lattice" (in en). Inorganic Chemistry 59 (12): 8054–8060. doi:10.1021/acs.inorgchem.0c00316. ISSN 0020-1669. PMID 32458677. https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c00316.
- ↑ Kampf, A. R.; Mills, S. J.; Nash, B. P. (October 2016). "Pauladamsite, Cu 4 (SeO 3 )(SO 4 )(OH) 4 ·2H 2 O, a new mineral from the Santa Rosa mine, Darwin district, California, USA" (in en). Mineralogical Magazine 80 (6): 949–958. doi:10.1180/minmag.2016.080.032. ISSN 0026-461X. Bibcode: 2016MinM...80..949K. https://www.cambridge.org/core/product/identifier/S0026461X00002504/type/journal_article.
- ↑ Xie, Yiming; Wu, Jihuai (2007). "Synthesis and Structure of a Cadmium Selenite-Sulfate Cd 4 (SeO 3) 2 (SO 4) 2". Bulletin-Korean Chemical Society 28 (8): 1416. doi:10.5012/bkcs.2007.28.8.1416. https://citeseerx.ist.psu.edu/document?repid=rep1&type=pdf&doi=c89e1ad72ae55269f7301b030ca913ea2cc903a4.
- ↑ 4.0 4.1 4.2 Li, Peng-Fei; Hu, Chun-Li; Kong, Fang; Mao, Jiang-Gao (2022). "Hg 2 (SeO 3 )(SO 4 ): the first sulfate selenite with large birefringence explored from d 10 transition metal compounds" (in en). Materials Chemistry Frontiers 6 (23): 3567–3576. doi:10.1039/D2QM00773H. ISSN 2052-1537. http://xlink.rsc.org/?DOI=D2QM00773H.
- ↑ Eaton, Teresa (2016). "Lanthanide and Actinide Selenites". https://diginole.lib.fsu.edu/islandora/object/fsu:366054/datastream/PDF/view.
- ↑ 6.0 6.1 6.2 Oyeka, Ebube E.; Winiarski, Michał J.; Świątek, Hanna; Balliew, Wyatt; McMillen, Colin D.; Liang, Mingli; Sorolla, Maurice; Tran, Thao T. (2022-11-25). "Ln 2 (SeO 3 ) 2 (SO 4 )(H 2 O) 2 (Ln=Sm, Dy, Yb): A Mixed‐Ligand Pathway to New Lanthanide(III) Multifunctional Materials Featuring Nonlinear Optical and Magnetic Anisotropy Properties" (in en). Angewandte Chemie 134 (48). doi:10.1002/ange.202213499. ISSN 0044-8249. Bibcode: 2022AngCh.13413499O.
- ↑ Genieva, S.; Yankova, R.; Baikusheva-Dimitrova, G.; Halachev, N. (June 2016). "Synthesis and characterization of Hf(SO4)2(H2O)4 and Hf(SeO3)(SeO4)(H2O)4" (in en). Journal of Thermal Analysis and Calorimetry 124 (3): 1595–1600. doi:10.1007/s10973-016-5275-3. ISSN 1388-6150. http://link.springer.com/10.1007/s10973-016-5275-3.
- ↑ Ren, Jinxuan; Chen, Yuqi; Ren, Liying; Zhou, Yuqiao; Dong, Xuehua; Gao, Daojiang; Huang, Ling; Cao, Liling et al. (2023-05-31). "Hg 3 (SeO 3 ) 2 (SO 4 ): A UV Nonlinear Optical Mercury Selenite Sulfate Constructed by Neat [Hg 6 O 8 (SeO 3 ) 4 ∞ Layers and SO 4 Tetrahedra"] (in en). Inorganic Chemistry 62 (23): 9130–9138. doi:10.1021/acs.inorgchem.3c00986. ISSN 0020-1669. PMID 37256655. https://pubs.acs.org/doi/10.1021/acs.inorgchem.3c00986.
- ↑ Kampf, A. R.; Mills, S. J.; Housley, R. M. (December 2010). "The crystal structure of munakataite, Pb 2 Cu 2 (Se 4+ O 3 )(SO 4 )(OH) 4 , from Otto Mountain, San Bernardino County, California, USA" (in en). Mineralogical Magazine 74 (6): 991–998. doi:10.1180/minmag.2010.074.6.991. ISSN 0026-461X. https://www.cambridge.org/core/product/identifier/S0026461X0005550X/type/journal_article.
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