Chemistry:Ruthenium(III) nitrate

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Ruthenium(III) nitrate
Names
Other names
Rhuthenium trinitrate, Ruthenium nitrate
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 239-923-0
Properties
Ru(NO3)3
Molar mass 287.1
Appearance Yellow crystals (hydrate)
Soluble
Hazards
GHS pictograms GHS03: OxidizingGHS05: CorrosiveGHS07: HarmfulGHS09: Environmental hazard
GHS Signal word Danger
H272, H302, H317, H318, H411
P210, P220, P221, P261, P264, P270, P272, P273, P280, P301+312, P302+352, P305+351+338, P310, P321, P330, P333+313, P363, P370+378, P391, P501
Related compounds
Related compounds
Americium(III) nitrate, Einsteinium(III) nitrate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Ruthenium(III) nitrate is an inorganic compound, a salt of ruthenium and nitric acid with the chemical formula Ru(NO3)3.[1][2]

Physical properties

Ruthenium(III) nitrate dissolves in water. It forms a crystalline hydrate with the composition Ru(NO
3
)
3
 · 6H2O
in the form of yellow crystals.

Chemical properties

Ruthenium(III) nitrate reacts with silicon oxide in a carbon monoxide atmosphere to form Ru(CO)
2
(OSi)
2
, Ru(CO)
3
(OSi)
2
, or Ru
3
(CO)
12
.[3]

Applications

Ruthenium(III) nitrate is used for the manufacture of ruthenium-carbon catalysts.[4]

References

  1. "Ruthenium Nitrate" (in en). American Elements. https://www.americanelements.com/ruthenium-nitrate-34513-98-9. 
  2. Becker, Harry; Dalpe, Claude; Walker, Richard J. (29 May 2002). "High-precision Ru isotopic measurements by multi-collector ICP-MS". The Analyst 127 (6): 775–780. doi:10.1039/b200596d. PMID 12146910. Bibcode2002Ana...127..775B. 
  3. Huang, Lin; Xu, Yide (November 2001). "Surface-mediated reductive carbonylation of SiO2-supported RuCl3 and Ru(NO)(NO3)3 studied by IR spectroscopy". Journal of Molecular Catalysis A: Chemical 176 (1–2): 267–280. doi:10.1016/S1381-1169(01)00267-9. https://www.sciencedirect.com/science/article/abs/pii/S1381116901002679. Retrieved August 21, 2021. 
  4. Kawaguchi, T; Sugimoto, W; Murakami, Y; Takasu, Y (1 January 2005). "Particle growth behavior of carbon-supported Pt, Ru, PtRu catalysts prepared by an impregnation reductive-pyrolysis method for direct methanol fuel cell anodes" (in en). Journal of Catalysis 229 (1): 176–184. doi:10.1016/j.jcat.2004.10.020. ISSN 0021-9517. https://www.sciencedirect.com/science/article/abs/pii/S0021951704005123. Retrieved 21 August 2021. 
Salts and covalent derivatives of the nitrate ion