Chemistry:Rhodium(III) perchlorate
From HandWiki
6(ClO4)3.svg)
| |
| Identifiers | |
|---|---|
3D model (JSmol)
|
|
PubChem CID
|
|
| |
| |
| Properties | |
| [Rh(H2O)6](ClO4)3 | |
| Appearance | yellow solid |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Rhodium(III) perchlorate refers to the inorganic compound with the formula Rh(H2O)6(ClO4)3. It is a hygroscopic yellow solid. It is the perchlorate salt of the tricationic aquo complex [Rh(H2O)6]3+. The compound is prepared by treating hydrated rhodium(III) chloride and perchloric acid at elevated temperatures:[1]
- [Rh(H2O)6]Cl3 + 3 HClO4 → [Rh(H2O)6](ClO4)3 + 3 HCl
The reaction of rhodium(III) hydroxide with concentrated perchloric acid also produce rhodium(III) perchlorate.[2]
- Rh(OH)3 + 3 HClO4 → Rh(ClO4)3 + 3 H2O
References
- ↑ Ayres, Gilbert H.; Forrester, John S. (1957). "The Preparation of Rhodium(III) Perchlorate Hexahydrate". Journal of Inorganic and Nuclear Chemistry 3: 365-366. doi:10.1016/0022-1902(57)80042-6.
- ↑ Gilbert H. Ayres, John S. Forrester. The preparation of rhodium(III) perchlorate hexahydrate. Journal of Inorganic and Nuclear Chemistry, 1957. Vol.3, Iss.6, pp 365-366
 |  |
