Chemistry:Rastsvetaevite

From HandWiki
Short description: Mineral of the eudialyte group
Rastsvetaevite
Rastsvetaevite-292890.jpg
Tiny dark pink grains of rastsvetaevite in matrix. Field of view 3 mm. From: Rasvumchorr Mt, Khibiny Massif, Murmansk Oblast, Russia
General
CategorySilicate mineral, Cyclosilicate
Strunz classification9.CO.10
Dana classification64.1b.1.2
Crystal systemTrigonal
Crystal classDitrigonal pyramidal (3m)
H-M symbol: (3m)
Space groupR3m
Unit cella = 14.25, c = 60.97 [Å] (approximated); Z = 3
Identification
ColorReddish-pink
Crystal habitirregular grains
FractureConchoidal
TenacityBrittle
Mohs scale hardness5-6
|re|er}}Vitreous
StreakWhite
DiaphaneityTransparent
Specific gravity2.86
Optical propertiesUniaxial (+)
Refractive indexnω = 1.60 nε = 1.60 (approximated)
References[1]

Rastsveatevite is a rare mineral of the eudialyte group with the chemical formula Na
27
K
8
Ca
12
Fe
3
Zr
6
Si
4
[Si
3
O
9
]
4
[Si
9
O
27
]
4
(O,OH,H
2
O)
6
Cl
2
. Its structure is modular.[3] It is only the third member of the group after andrianovite and davinciite with essential (site-dominating) potassium.[1] Potassium and sodium enter both N4 and M2 sites.[4] The mineral is named after Russian crystallographer Ramiza K. Rastsvetaeva.[1]

Occurrence and association

Rastsvetaevite was originally found in hyperagpaitic (ultra-alkaline) pegmatite at Mt. Rasvumchorr, Khibiny massif, Kola Peninsula, Russia. Associated minerals are aegirine, nacaphite, nepheline, natrite, schcherbakovite, sodalite, villiaumite, and rasvumite.[1]

Notes on crystal structure

The c unit cell parameter in rastsvetaevite is doubled.[1]

References

  1. 1.0 1.1 1.2 1.3 1.4 Mindat, http://www.mindat.org/min-26586.html
  2. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode2021MinM...85..291W. 
  3. Khomyakov, A.P.; Nechelyustov, G.N.; Arakcheeva, A.V. (2006). "Rastsvetaevite, Na27K8Ca12Fe3Zr6Si4[Si3O9]4[Si9O27]4(O,OH,H2O)6Cl2, a new mineral with a modular eudialyte-like structure and crystal-chemical systematics of the eudialyte group". Proceedings of the Russian Mineralogical Society 135 (1): 49–65. 
  4. Johnsen, O.; Ferraris, G.; Gault, R. A.; Grice, J. D.; Kampf, A. R.; Pekov, I. V. (2003-06-01). "The nomenclature of eudialyte-group minerals". The Canadian Mineralogist 41 (3): 785–794. doi:10.2113/gscanmin.41.3.785. ISSN 0008-4476. Bibcode2003CaMin..41..785J.