Chemistry:Pibocin B

Pibocin B
Names
	Preferred IUPAC name (6aR,9R,10aR)-5-Bromo-4-methoxy-7,9-dimethyl-4,6,6a,7,8,9,10,10a-octahydroindolo[4,3-fg]quinoline
Identifiers
3D model (JSmol)	Interactive image;
ChEMBL	ChEMBL491189;
ChemSpider	8150686;
PubChem CID	9975094;
	InChI InChI=1S/C17H21BrN2O/c1-10-7-12-11-5-4-6-14-16(11)13(17(18)20(14)21-3)8-15(12)19(2)9-10/h4-6,10,12,15H,7-9H2,1-3H3/t10-,12-,15-/m1/s1 Key: ZCNGIHGSYMIIIR-IXPVHAAZSA-N; InChI=1/C17H21BrN2O/c1-10-7-12-11-5-4-6-14-16(11)13(17(18)20(14)21-3)8-15(12)19(2)9-10/h4-6,10,12,15H,7-9H2,1-3H3/t10-,12-,15-/m1/s1 Key: ZCNGIHGSYMIIIR-IXPVHAAZBZ;
	SMILES C[C@@H]1C[C@H]2[C@@H](CC3=C(N(C4=CC=CC2=C34)OC)Br)N(C1)C;
Properties
Chemical formula	C17H21BrN2O
Molar mass	349.272 g·mol−1
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
	Infobox references

Pibocin B is an alkaloid isolated from an ascidian in the genus Eudistoma.^[1]^[2]

References

↑ Makarieva, T. N.; Dmitrenok, A. S.; Dmitrenok, P. S.; Grebnev, B. B.; Stonik, V. A. (2001). "Pibocin B, the first N-O-methylindole marine alkaloid, a metabolite from the Far-Eastern ascidian Eudistoma species". Journal of Natural Products 64 (12): 1559–61. doi:10.1021/np010161w. PMID 11754612.
↑ Liu, Haichao; Zhang, Xiwu; Shan, Dong; Pitchakuntla, Mallesham; Ma, Yongfan; Jia, Yanxing (16 June 2017). "Total Syntheses of Festuclavine, Pyroclavine, Costaclavine, epi -Costaclavine, Pibocin A, 9-Deacetoxyfumigaclavine C, Fumigaclavine G, and Dihydrosetoclavine". Organic Letters 19 (12): 3323–3326. doi:10.1021/acs.orglett.7b01504.

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