Chemistry:Oxalyldihydrazide
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| Preferred IUPAC name
Oxalohydrazide[1] | |
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| Properties | |
| C2H6N4O2 | |
| Molar mass | 118.096 g·mol−1 |
| Melting point | 242–244 °C (468–471 °F; 515–517 K) |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
 verify (what is   ?)
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Oxalyldihydrazide is an organic compound with the formula of NH2NHCOCONHNH2. Oxalyldihydrazide can act as a ligand on some divalent first row transition metals like manganese, iron, cobalt, nickel, copper or zinc.[2] Oxalyldihydrazide is a colorless or white solid that is poorly soluble in cold water and insoluble in most organic solvents.[3]
Synthesis
Oxalyldihydrazide can be prepared by the reaction of hydrazine hydrate with an oxalate ester in alcoholic solution at room temperature.[3]
References
- ↑ International Union of Pure and Applied Chemistry (2014). Nomenclature of Organic Chemistry: IUPAC Recommendations and Preferred Names 2013. The Royal Society of Chemistry. pp. 872. doi:10.1039/9781849733069. ISBN 978-0-85404-182-4.
- ↑ Aggarwal, R. C.; Singh, Bachcha (October 1978). "Synthesis and structural studies of oxalyldihydrazide complexes of Mn(II), Fe(II), Co(II), Ni(II), Cu(II), and Zn(II)". Zeitschrift für anorganische und allgemeine Chemie 445 (1): 227–232. doi:10.1002/zaac.19784450129.
- ↑ 3.0 3.1 Curtius, Th.; Heidenreich, K. (1895-09-12). "Hydrazide und Azide organischer Säuren. XI Abhandlung. 36. Die Hydrazide und Azide der Kohlensäure" (in en). Journal für Praktische Chemie 52 (1): 454–489. doi:10.1002/prac.18950520135. ISSN 0021-8383. https://onlinelibrary.wiley.com/doi/10.1002/prac.18950520135.
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