Chemistry:Nitrate selenite

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The nitrate selenites are mixed anion compounds containing distinct nitrate (NO3)and selenite (SO32−) groups. The compounds are colourless unless coloured by cations.

List

formula formula weight crystal system space group unit cell Å volume density comment reference
[Cu(HSeO3)2(NO3)2]2−•2NH4+•NH4NO3 orthorhombic Pnma a=8.8813 b=24.01 c=7.2195 [1]
(RbNO3)2[Cu(HSeO3)2] monoclinic P21/c a=9.2833 b=7.1193 c=9.0315 β=91.643° [2]
Ag5Cu2(NO3)(SeO3)4 1326.26 triclinic P1 a=5.148 b=7.050 c=10.540 α=73.09° β=89.08° γ=88.50° 365.85 5.61 [3]
Cd(HSeO3)NO3 302.38 orthorhombic Pbca a=6.359 b=8.945 c=16.648 Z=8 949.1 4.23 [4]
(CsNO3)[Cu(HSeO3)2] orthorhombic Pnma a=8.891 b=13.859 c=7.249 [2]
Gd(NO3)(Se2O5)•3H2O orthorhombic P212121 a=6.2509 b=7.0944 c=20.747 SHG 0.2 × KDP [5]
Lu(SeO3)(NO3)(H2O) 381.96 orthorhombic Pbcn a=16.151 b=11.854 c=6.795 Z=8 1300.9 3.900 colourless [6]
(TlNO3)[Cu(HSeO3)2] orthorhombic Pnma a=8.7788 b=13.668 c=7.2056 [2]
Pb2(SeO3)(NO3)2 orthorhombic Pmn21 a = 5.4669 b = 10.3277 c = 7.2610 Z = 4 409.96 [7][8]
Pb2(NO2)(NO3)(SeO3) orthorhombic Pmn21 a=5.529 b=10.357 c=6.811 Z=2 [9]
PbCu3(OH)(NO3)(SeO3)3•0.5H2O triclinic P1 a=7.761 b=9.478 c=9.514 α=66.94° β=69.83° γ=81.83° Z=2 [3][10]
Pb2Cu3O2(NO3)2(SeO3)2 orthorhombic Cmc21 a=5.884 b=12.186 c=19.371 Z=4 [3][10]
Pb(OF)Cu3(SeO3)2(NO3) 748.74 R3m a=6.6973 c=18.5548 Z=3 720.75 5.175 dark brown [11]
PbCdF(SeO3)(NO3) orthorhombic Pca21 a=11.121 b=10.366 c=5.3950 Z=4 621.9 5.634 SHG 2.6×KDP band gap 4.42 eV [12]
Bi(SeO3)(NO3) monoclinic C2/c a=15.352 b=4.9112 c=14.101 β=110.79° [13]
(Bi3O2)(SeO3)2(NO3) monoclinic P21/c a=9.9403 b=9.6857 c=10.6864 β=93.115° Z=4 [14]
((CH3)4N)[UO2(NO3)(SeO3)] monoclinic C2/m a = 21.888 b = 6.9501 c = 8.349 β = 97.618° Z = 4 1259.0 2.813 yellow-green [15]
(H2en)[(UO2)(SeO3)(HSeO3)](NO3)·0.5H2O 1316.19 orthorhombic Pbca a = 13.170 b = 11.055 c = 18.009 Z = 4 2621.8 3.334 [16]

References

  1. Lafront, A.M.; Trombe, J.C. (June 1995). "'Layered hydrogenselenite' I. Synthesis, structure redetermination of [Cu(HSeO3)2(H2O)2 and determination of [Cu(HSeO3)2(NO3)2]2−·2NH4+,NH4NO3. Structural relationships of these complexes with [Cu(HSeO3)2]"] (in en). Inorganica Chimica Acta 234 (1–2): 19–25. doi:10.1016/0020-1693(95)04500-9. https://linkinghub.elsevier.com/retrieve/pii/0020169395045009. 
  2. 2.0 2.1 2.2 Markovski, Mishel R.; Charkin, Dmitri O.; Siidra, Oleg I.; Nekrasova, Diana O. (2019-12-18). "Copper hydroselenite nitrates ( A + NO 3 ) n [Cu(HSeO 3 ) 2 ( A =Rb + , Cs + and Tl + , n =1, 2) related to Ruddlesden – Popper phases"] (in en). Zeitschrift für Kristallographie - Crystalline Materials 234 (11–12): 749–756. doi:10.1515/zkri-2019-0036. ISSN 2196-7105. https://www.degruyter.com/document/doi/10.1515/zkri-2019-0036/html. 
  3. 3.0 3.1 3.2 Effenberger, H. (1991-12-15). "Structure of pentasilver(I) dicopper(II) mononitrate tetraselenite(IV)". Acta Crystallographica Section C Crystal Structure Communications 47 (12): 2522–2525. doi:10.1107/S0108270191006935. Bibcode1991AcCrC..47.2522E. https://scripts.iucr.org/cgi-bin/paper?S0108270191006935. 
  4. Leskela, Markku; Valkonen, Jussi; Leskela, Tuula (1984). "The crystal structure, thermal behaviour and IR spectrum of cadmium hydrogenselenite nitrate". Acta Chemica Scandinavica A 38: 233–239. doi:10.3891/acta.chem.scand.38a-0233. http://actachemscand.org/pdf/acta_vol_38a_p0233-0239.pdf. 
  5. Wu, Chao; Li, Longhua; Lin, Lin; Huang, Zhipeng; Humphrey, Mark G.; Zhang, Chi (2020). "Gd(NO 3 )(Se 2 O 5 )·3H 2 O: a nitrate–selenite nonlinear optical material with a short ultraviolet cutoff edge". Dalton Transactions 49 (10): 3253–3259. doi:10.1039/D0DT00116C. PMID 32096527. 
  6. Wu, Chao; Li, Longhua; Lin, Lin; Huang, Zhipeng; Humphrey, Mark G.; Zhang, Chi (2020-04-14). "Enhancement of Second-Order Optical Nonlinearity in a Lutetium Selenite by Monodentate Anion Partial Substitution" (in en). Chemistry of Materials 32 (7): 3043–3053. doi:10.1021/acs.chemmater.0c00034. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/acs.chemmater.0c00034. 
  7. Meng, Chang-Yu; Geng, Lei; Chen, Wen-Ting; Wei, Ming-Fang; Dai, Kai; Lu, Hong-Yan; Cheng, Wen-Dan (August 2015). "Syntheses, structures, and characterizations of a new second-order nonlinear optical material: Pb2(SeO3)(NO3)2". Journal of Alloys and Compounds 640: 39–44. doi:10.1016/j.jallcom.2015.04.021. 
  8. Meng, Chang-Yu; Geng, Lei; Chen, Wen-Ting; Wei, Ming-Fang; Dai, Kai; Lu, Hong-Yan; Cheng, Wen-Dan (August 2015). "Syntheses, structures, and characterizations of a new second-order nonlinear optical material: Pb2(SeO3)(NO3)2" (in en). Journal of Alloys and Compounds 640: 39–44. doi:10.1016/j.jallcom.2015.04.021. https://linkinghub.elsevier.com/retrieve/pii/S0925838815009627. 
  9. Effenberger, Herta (February 1987). "Darstellung und Kristallstruktur von Pb2(NO2)(NO3)(SeO3)" (in de). Monatshefte für Chemie Chemical Monthly 118 (2): 211–216. doi:10.1007/BF00810054. ISSN 0026-9247. http://link.springer.com/10.1007/BF00810054. 
  10. 10.0 10.1 Effenberger, Herta (October 1986). "PbCu3(OH)(NO3)(SeO3)3·1/2H2O und Pb2Cu3O2(NO3)2(SeO3)2: Synthese und Kristallstrukturuntersuchung" (in de). Monatshefte für Chemie - Chemical Monthly 117 (10): 1099–1106. doi:10.1007/BF00811322. ISSN 0026-9247. http://link.springer.com/10.1007/BF00811322. 
  11. Zhang, Mengsi; Zhao, Zhiying; Zhang, Wanwan; Li, Jinyang; Huang, Xiaoying; He, Zhangzhen (2020). "Pb(OF)Cu 3 (SeO 3 ) 2 (NO 3 ): a selenite fluoride nitrate with a breathing kagomé lattice" (in en). Chemical Communications 56 (80): 11965–11968. doi:10.1039/D0CC03684F. ISSN 1359-7345. PMID 33033813. http://xlink.rsc.org/?DOI=D0CC03684F. 
  12. Ma, Yun-Xiang; Hu, Chun-Li; Li, Bing-Xuan; Kong, Fang; Mao, Jiang-Gao (2018-09-17). "PbCdF(SeO 3 )(NO 3 ): A Nonlinear Optical Material Produced by Synergistic Effect of Four Functional Units" (in en). Inorganic Chemistry 57 (18): 11839–11846. doi:10.1021/acs.inorgchem.8b02044. ISSN 0020-1669. PMID 30160946. 
  13. Song, Jun-Ling; Qian, Cheng (February 2017). "Syntheses, Crystal Structures, and Properties of Two Quaternary Selenite/Tellurite-Nitrates with Formula of Bi(SeO 3 )(NO 3 ) and Bi 3 (μ 3 -OH)(TeO 3 ) 3 (NO 3 ) 2" (in en). ChemistrySelect 2 (4): 1681–1685. doi:10.1002/slct.201601967. ISSN 2365-6549. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/slct.201601967. 
  14. Meng, Chang-Yu; Wei, Ming-Fang; Geng, Lei; Hu, Pei-Qing; Yu, Meng-Xia; Cheng, Wen-Dan (July 2016). "Synthesis, structure, and characterization of two new bismuth(III) selenite/tellurite nitrates: [(Bi3O2)(SeO3)2(NO3) and [Bi(TeO3)](NO3)"] (in en). Journal of Solid State Chemistry 239: 46–52. doi:10.1016/j.jssc.2016.04.013. https://linkinghub.elsevier.com/retrieve/pii/S0022459616301360. 
  15. Liu, Dong-Sheng; Huang, Gan-Sheng; Luo, Qiu-Yan; Xu, Ya-Ping; Li, Xin-Fa (2006-07-01). "Poly[tetramethylammonium [nitratouranyl-μ 3 -selenito]]". Acta Crystallographica Section e Structure Reports Online 62 (7): m1584–m1585. doi:10.1107/S1600536806022045. ISSN 1600-5368. https://scripts.iucr.org/cgi-bin/paper?S1600536806022045. 
  16. Liu, Dong-Sheng; Kuang, Han-Mao; Chen, Wen-Tong; Luo, Qiu-Yan; Sui, Yan (September 2015). "Synthesis, Structure, and Photoluminescence Properties of an Organically-Templated Uranyl Selenite" (in en). Zeitschrift für anorganische und allgemeine Chemie 641 (11): 2009–2013. doi:10.1002/zaac.201500277. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.201500277. 
Salts and covalent derivatives of the nitrate ion