Chemistry:Hexa-cata-hexabenzocoronene

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Hexa-cata-hexabenzocoronene
Hexa-cata-hexabenzocoronene.png
Names
Preferred IUPAC name
Trinaphtho[1,2,3,4-fgh:1′,2′,3′,4′-pqr:1′′,2′′,3′′,4′′-za1b1]trinaphthylene
Other names
Hexabenzo[a,d,g,j,m,p]coronene
Identifiers
3D model (JSmol)
ChemSpider
UNII
Properties
C48H24
Molar mass 600.720 g·mol−1
Appearance Yellow–orange solid[1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Hexa-cata-hexabenzocoronene (hexabenzo[a,d,g,j,m,p]coronene) is a polycyclic aromatic hydrocarbon with the molecular formula C48H24. It consists of a central coronene molecule, with an additional benzene ring fused onto each ring around the periphery.

Hexa-cata-hexabenzocoronene has a contorted structure due to steric crowding among the benzene rings around the edge,[2] analogous to the situation in benzo[c]phenanthrene.

See also

References

  1. Xiao, Shengxiong; Myers, Matthew; Miao, Qian; Sanaur, Sébastien; Pang, Keliang; Steigerwald, Michael L.; Nuckolls, Colin (2005). "Molecular Wires from Contorted Aromatic Compounds". Angew. Chem. Int. Ed. Engl. 44 (45): 7390–7394. doi:10.1002/anie.200502142. PMID 16173105. 
  2. Chiu, Chien-Yang; Kim, Bumjung; Gorodetsky, Alon A.; Sattler, Wesley; Wei, Sujun; Sattler, Aaron; Steigerwald, Michael; Nuckolls, Colin (2011). "Shape-shifting in contorted dibenzotetrathienocoronenes". Chem. Sci. 2: 1480–1486. doi:10.1039/C1SC00156F. 

External links