Chemistry:Ferrario-Ackermann reaction

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Ferrario-Ackermann reaction
Named after M. E. Ferrario
Fritz Ackermann
Reaction type Ring forming reaction

In organic chemistry, the Ferrario-Ackermann reaction or simply the Ferrario reaction is a name reaction that allow for the generation of phenoxanthiine from diphenyl ether and sulfur in the presence of aluminum chloride catalyst.[1][2][3][4][5][6]

Ferrario reaction


References

  1. Ferrario, E. (January 1911). "Preparation of phenoxathiin from diphenyl ether and sulfur". Bulletin de la Société Chimique de France 9 (4): 536-537. https://gallica.bnf.fr/ark:/12148/bpt6k282044r.image.f540.langEN. 
  2. Fritz Ackermann, "Verfahren zur Darstellung von Phenoxthin und dessen Derivaten", Germany patent 234743, published 20 May 1911
  3. Deasy, Clara L. (1 April 1943). "The Chemistry of Phenoxathiin and its Derivatives". Chemical Reviews 32 (2): 173-194. doi:10.1021/cr60102a001. 
  4. Suter, C. M.; Maxwell, Charles E.. "Phenoxthin [Phenoxathiin"]. Organic Syntheses 18: 64. doi:10.15227/orgsyn.018.0064. http://www.orgsyn.org/demo.aspx?prep=CV2P0485. ; Collective Volume, 2, pp. 485 
  5. Al-Araji, Suad M.; Mohamad, Ayad Ahmed (2 June 201). "Synthesis of New Pyrazoline - Phenoxathiin Derivatives". Baghdad Science Journal 10 (2): 405-419. doi:10.21123/bsj.2013.10.2.405-419. https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/1464. 
  6. Suter, C. M.; Green, Frank O. (1 December 1937). "Phenoxthin. II. Extension of the Ferrario Reaction". Journal of the American Chemical Society 59 (12): 2578–2580. doi:10.1021/ja01291a030.