Chemistry:Ethylene trithiocarbonate

From HandWiki
Ethylene trithiocarbonate
C2H4S2CS.svg
Names
Other names
1,3-dithiolane-2-thione
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 212-498-9
UNII
Properties
C3H4S3
Molar mass 136.25 g·mol−1
Appearance yellow solid
Melting point 37 °C (99 °F; 310 K)
Boiling point 95–105 °C (203–221 °F; 368–378 K) 0.01 torr
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Tracking categories (test):

Ethylene trithiocarbonate is an organosulfur compound with the formula C
2
H
4
S
2
CS
.[1] This yellow solid is prepared by alkylation of trithiocarbonate with 1,2-dibromoethane.[2] Ethylene trithiocarbonate is an intermediate in the synthesis of tetrathiafulvalene and its derivatives.[3]

References

  1. Fallah-Mehrjardi, Mehdi (2018). "Review of the organic trithiocarbonates synthesis". Monatshefte für Chemie - Chemical Monthly 149 (11): 1931–1944. doi:10.1007/s00706-018-2256-1. 
  2. Lee, Albert W. M.; Chan, W. H.; Wong, H. C. (1988). "One Pot Phase Transfer Synthesis of Trithiocarbonates from Carbon Bisulphide and Alkyl Halides". Synthetic Communications 18 (13): 1531–1536. doi:10.1080/00397918808081310. 
  3. Gorgues, Alain; Hudhomme, Piétrick; Sallé, Marc (2004). "Highly Functionalized Tetrathiafulvalenes: Riding along the Synthetic Trail from Electrophilic Alkynes". Chemical Reviews 104 (11): 5151–5184. doi:10.1021/cr0306485. PMID 15535646.