Chemistry:Earlandite

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Earlandite
Ca-citrate-tetrahydrate.png
General
CategoryOrganic minerals
Formula
(repeating unit)
[Ca3(C6H5O7)2(H2O)2]·2H2O
Strunz classification10.AC.15
Crystal systemTriclinic
Space groupP1 (No. 2)
Unit cella = 5.9466(4), b = 10.2247(8)
c = 16.6496(13) [Å]; Z = 2
Identification
ColorWhite, pale yellow
Crystal habitNodular
StreakWhite
DiaphaneityTransparent
Specific gravity1.80–1.95 (measured), 2.00 (calculated)
Optical propertiesBiaxial (+)
Refractive indexnα = 1.515
nβ = 1.530
nγ = 1.580
Birefringenceδ = 0.065
2V angle60°
Diagnostic featuresFine-grained and wart-like nodule crystal habit
SolubilityInsoluble
References[1][2][3][4]

Earlandite, [Ca3(C6H5O7)2(H2O)2]·2H2O, is the mineral form of calcium citrate tetrahydrate. It was first reported in 1936 and named after the English microscopist and oceanographer Arthur Earland FRSE. Earlandite occurs as warty fine-grained nodules ca. 1 mm in size in bottom sediments of the Weddell Sea, off Antarctica.[3] Its crystal symmetry was first assigned as orthorhombic, then as monoclinic, and finally as triclinic.[1]

References

  1. 1.0 1.1 Herdtweck, Eberhardt; Kornprobst, Tobias; Sieber, Roland; Straver, Leo; Plank, Johann (2011). "Crystal Structure, Synthesis, and Properties of tri-Calcium di-Citrate tetra-Hydrate [Ca3(C6H5O7)2(H2O)2]·2H2O". Z. Anorg. Allg. Chem. 637 (6): 655–659. doi:10.1002/zaac.201100088. 
  2. Earlandite. Mindat.org
  3. 3.0 3.1 "Earlandite". Handbook of Mineralogy. V (Borates, Carbonates, Sulfates). Chantilly, VA, US: Mineralogical Society of America. 2003. ISBN 0962209740. http://rruff.info/doclib/hom/earlandite.pdf. 
  4. Earlandite. Webmineral
  5. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode2021MinM...85..291W. 

Bibliography

  • Palache, P.; Berman H.; Frondel, C. (1960). "Dana's System of Mineralogy, Volume II: Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. (Seventh Edition)" John Wiley and Sons, Inc., New York, pp. 1105-1106.