Chemistry:Caesium triiodide
From HandWiki
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3D model (JSmol)
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PubChem CID
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| Properties | |
| CsI3 | |
| Molar mass | 513.61886 g·mol−1 |
| Appearance | purple[1] |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
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Caesium triiodide is an inorganic compound, with the chemical formula of CsI3. It can be prepared by slow volatilization and crystallization of caesium iodide and iodine in aqueous ethanol solution.[2] It can form precipitates with diazobenzene.[3]
It undergoes a phase transition from Pnma to P-3c1 under high pressure, and its structure changes from layered to 3D.[4]
References
- ↑ Ronald Rich (22 December 2007). Inorganic Reactions in Water. Springer. pp. 472. ISBN 978-3-540-73962-3. https://books.google.com/books?id=Dv_F03cdKPUC&pg=PA472. Retrieved 2022-09-12.
- ↑ Richard M. Bozorth, Linus Pauling (Jun 1925). "The Crystal Structures of Cesium Tri-Iodide and Cesium Dibromo-Iodide" (in en). Journal of the American Chemical Society 47 (6): 1561–1571. doi:10.1021/ja01683a009. ISSN 0002-7863. https://pubs.acs.org/doi/abs/10.1021/ja01683a009. Retrieved 2022-09-09.
- ↑ H. F. Halliwell, S. C. Nyburg (1960). "891. The reaction of the benzenediazonium ion with certain anions in aqueous acid solution" (in en). Journal of the Chemical Society (Resumed): 4603–4608. doi:10.1039/jr9600004603. ISSN 0368-1769. http://xlink.rsc.org/?DOI=jr9600004603. Retrieved 2022-09-09.
- ↑ Tomasz Porȩba, Stefano Racioppi, Gaston Garbarino, Wolfgang Morgenroth, Mohamed Mezouar (2022-07-18). "Investigating the Structural Symmetrization of CsI 3 at High Pressures through Combined X-ray Diffraction Experiments and Theoretical Analysis" (in en). Inorganic Chemistry 61 (28): 10977–10985. doi:10.1021/acs.inorgchem.2c01690. ISSN 0020-1669. PMID 35792580. https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c01690. Retrieved 2022-09-09.
| HI | He | ||||||||||||||||
| LiI | BeI2 | BI3 | CI4 | NI3 | I2O4, I2O5, I4O9 |
IF, IF3, IF5, IF7 |
Ne | ||||||||||
| NaI | MgI2 | AlI3 | SiI4 | PI3, P2I4 |
S | ICl, ICl3 |
Ar | ||||||||||
| KI | CaI2 | Sc | TiI4 | VI3 | CrI3 | MnI2 | FeI2 | CoI2 | NiI2 | CuI | ZnI2 | Ga2I6 | GeI2, GeI4 |
AsI3 | Se | IBr | Kr |
| RbI | SrI2 | YI3 | ZrI4 | NbI5 | Mo | Tc | Ru | Rh | Pd | AgI | CdI2 | InI3 | SnI4, SnI2 |
SbI3 | TeI4 | I | Xe |
| CsI | BaI2 | HfI4 | TaI5 | W | Re | Os | Ir | Pt | AuI | Hg2I2, HgI2 |
TlI | PbI2 | BiI3 | Po | AtI | Rn | |
| Fr | RaI2 | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |
| ↓ | |||||||||||||||||
| La | Ce | Pr | Nd | Pm | SmI2 | Eu | Gd | TbI3 | Dy | Ho | Er | Tm | Yb | Lu | |||
| Ac | ThI4 | Pa | UI3, UI4 |
Np | Pu | Am | Cm | Bk | Cf | EsI3 | Fm | Md | No | Lr | |||
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