Chemistry:Breyite

From HandWiki
Breyite
General
CategoryMineral
Formula
(repeating unit)
Ca3.01(2)Si2.98(2)O9
Crystal systemTriclinic
Space groupP1
Unit cella0 = 6.6970(4) Å,

b0= 9.2986(7) Å,
c0 = 6.6501(4) Å,
α = 83.458(6)°,
β = 76.226(6)°,

γ = 69.581(7)°
Identification
Colourcolorless
Cleavagenot observed
|re|er}}vitreous
Density3.072 g/cm3
Ultraviolet fluorescencenon-fluorescent
References[1]

Breyite is a high pressure calcium silicate mineral (CaSiO3) found in diamond inclusions.[3][4] It is the second most abundant inclusion after ferropericlase, for diamonds with a deep Earth origin.[5][4] Its occurrence can also indicate the host diamond's super-deep origin. This mineral is named after German mineralogist, petrologist and geochemist Gerhard P. Brey.

CaSiO3 phase diagram showing Breyite is stable around 3-9 GPa[6]

References

  1. Brenker, Frank E.; Nestola, Fabrizio; Brenker, Lion; Peruzzo, Luca; Harris, Jeffrey W. (1 January 2021). "Origin, properties, and structure of breyite: The second most abundant mineral inclusion in super-deep diamonds". American Mineralogist 106 (1): 38–43. doi:10.2138/am-2020-7513. Bibcode2021AmMin.106...38B. 
  2. "Breyite". https://www.mindat.org/min-53167.html. 
  3. Alderton, David; Elias, Scott (2020) (in en). Encyclopedia of Geology. Elsevier Science. pp. 467. ISBN 9780081029091. 
  4. 4.0 4.1 Brenker, Frank E.; Nestola, Fabrizio; Brenker, Lion; Peruzzo, Luca; Harris, Jeffrey W. (2021-01-01). "Origin, properties, and structure of breyite: The second most abundant mineral inclusion in super-deep diamonds" (in en). American Mineralogist 106 (1): 38–43. doi:10.2138/am-2020-7513. ISSN 1945-3027. Bibcode2021AmMin.106...38B. https://www.degruyter.com/document/doi/10.2138/am-2020-7513/html. 
  5. "Breyite". https://www.mindat.org/min-53167.html. 
  6. Milani, Sula; Comboni, Davide; Lotti, Paolo; Fumagalli, Patrizia; Ziberna, Luca; Maurice, Juliette; Hanfland, Michael; Merlini, Marco (2021-06-19). "Crystal Structure Evolution of CaSiO3 Polymorphs at Earth's Mantle Pressures". Minerals 11 (6): 652. doi:10.3390/min11060652. ISSN 2075-163X. Bibcode2021Mine...11..652M.