Chemistry:Borate nitrate

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Borate nitrates are mixed anion compounds containing separate borate and nitrate anions. They are distinct from the boronitrates where the borate is linked to a nitrate via a common oxygen atom.

List

chem mw crystal system space group unit cell Å volume density comment references
Na3(NO3)[B6O10] [1]
K3B6O10NO3 [2]
K3Na[B6O9(OH)3]NO3 Pnnm a=13.208, b=9.107, c=12.325 Z=4 [3]
Co3B7O13NO3 [4]
[Co(H2O)6](NO3)2·[Co{B3O3(OH)4}2(H2O)4]·2H2O [5]
[Ni(H2O)6](NO3)2·[Ni{B3O3(OH)4}2(H2O)4]·2H2O [5]
Ni3B7O13NO3 [4]
K7Ni[B18O24(OH)9](NO3)6· (H3BO3) 1497.96 trigonal R3 a=12.2229 c=54.784 Z=6 7088 2.11 green [6]
Cu3B7O13NO3 [4]
Zn3B7O13NO3 [4]
[Zn(H2O)6](NO3)2·[Zn{B3O3(OH)4}2(H2O)4]·2H2O monoclinic P21/c a = 11.282, b = 6.5374, c = 17.668, β = 100.981° [5]
Rb3(NO3)[B6O10] [2]
Cd3B7O13NO3 [4]
La[B5O8(OH)]NO3
La[B5O8(OH)]NO3·2H2O monoclinic P21/n a=6.540, b=15.550, c=10.672, β=90.44° and Z=4 [7]
cerium(III) aquahydroxidooctaoxidopentaborate nitrate dihydrate Ce[B5O8(OH)(H2O)]NO3·2H2O 455.24 monoclinic P21/n a=6.444 b=15.572 c=10.745 β=90.395 Z=4 1078.2 2.904 colourless [8]
Pr[B5O8(OH)(H2O)x]NO3·2H2O monoclinic P21/n a=6.419, b=15.518, c=10.684, with β=90.54° Z=4 1064.3 [9]
Pr7(BO3)3(NO3)N3O hexagonal P63 a=10.6834 c=6.6752 Z=2 6.457 green; contains N(OBO3)3 clusters, oxide and nitride [10]
Nd7(BO3)3(NO3)N3O hexagonal P63 a=10.6446 c=6.6339 Z=2 6.664 purplish-blue;contains N(OBO3)3 clusters oxide, and nitride;SHG [10]
Nd[B5O8(OH)(H2O)x]NO3·2H2O P21/n a = 6.4285, b = 15.5258, c = 10.7052, β = 90.39° 1068.44 [11]
Sm[B5O8(OH)(H2O)x]NO3·2H2O P21/n a = 6.4409, b = 15.4199, c = 10.5097, β = 90.33° 1043.79 [11]
Lu2B2O5(NO3)2·2H2O triclinic P1 a=7.8952, b=9.8862, c=14.6033, α=90.83, β=101.75, γ=110.02° Z=4 [6][12]
Pb2(BO3)(NO3) 535.20 hexagonal P63mc a=5.0731 c=13.040 Z=2 290.64 6.116 colourless SHG 9×KDP [13]
[Pb3(B3O7)](NO3) 828.01 Pnma a=10.3481 b=7.8908 c=11.2123 Z=4 914.54 6.007 colourless [14]

References

  1. ↑ Ortner, Teresa S.; Schildhammer, Daniel; Tribus, Martina; Joachim, Bastian; Huppertz, Hubert (2017-03-01). "Synthesis and characterization of the alkali borate-nitrates Na3–x Kx[B6O10NO3 (x=0.5, 0.6, 0.7)"]. Zeitschrift für Naturforschung B 72 (3): 215–223. doi:10.1515/znb-2016-0242. ISSN 1865-7117. http://www.degruyter.com/view/j/znb.2017.72.issue-3/znb-2016-0242/znb-2016-0242.xml. 
  2. ↑ 2.0 2.1 Zhang, Qiqi; Zhang, Fangfang; Li, Fuming; Han, Shujuan; Yang, Zhihua; Pan, Shilie (2021-02-13). "M3B6O10NO3 (M = K, Rb): Two new alkali metal borate‐nitrates with noncentrosymmetric structures" (in en). European Journal of Inorganic Chemistry 2021 (13): 1297–1304. doi:10.1002/ejic.202001167. ISSN 1434-1948. https://onlinelibrary.wiley.com/doi/10.1002/ejic.202001167. 
  3. ↑ Ortner, Teresa S.; Wurst, Klaus; Perfler, Lukas; Tribus, Martina; Huppertz, Hubert (January 2015). "Hydrothermal synthesis and characterization of the first mixed alkali borate-nitrate K3Na[B6O9(OH)3]NO3" (in en). Journal of Solid State Chemistry 221: 66–72. doi:10.1016/j.jssc.2014.09.016. Bibcode: 2015JSSCh.221...66O. 
  4. ↑ 4.0 4.1 4.2 4.3 4.4 Bither, Tom A.; Young, Howard S. (1974-08-01). "Nitrato- and fluoroboracites M3B7O13NO3 and M3B7O13F" (in en). Journal of Solid State Chemistry 10 (4): 302–311. doi:10.1016/0022-4596(74)90039-5. ISSN 0022-4596. Bibcode: 1974JSSCh..10..302B. https://dx.doi.org/10.1016%2F0022-4596%2874%2990039-5. 
  5. ↑ 5.0 5.1 5.2 Liu, Ying; Deng, Jun-Xia; Pan, Chun-Yang (2020-05-04). "Synthesis and Structural Manipulation of a Polyanionic Zincoborate [Zn(H2O)6(NO3)2·[Zn{B3O3(OH)4}2(H2O)4]·2H2O by the Molten Salt Method and its Potential Application as a Flame Retardant"] (in en). Journal of Cluster Science 32 (2): 469–477. doi:10.1007/s10876-020-01806-7. ISSN 1040-7278. http://link.springer.com/10.1007/s10876-020-01806-7. 
  6. ↑ 6.0 6.1 Zoller, Michael; Wurst, Klaus; Huppertz, Hubert (2019-10-25). "Synthesis of the first nickel borate nitrate K7Ni[B18O24(OH)9](NO3)6· (H3BO3)". Zeitschrift für Naturforschung B 74 (10): 757–764. doi:10.1515/znb-2019-0126. ISSN 1865-7117. open access CC-BY can use images
  7. ↑ Zhao, Biao-Chun; Sun, Wei; Ren, Wei-Jian; Huang, Ya-Xi; Li, Zucheng; Pan, Yuanming; Mi, Jin-Xiao (October 2013). "Hygroscopic La[B5O8(OH)]NO3·2H2O: Insight into the evolution of borate fundamental building blocks" (in en). Journal of Solid State Chemistry 206: 91–98. doi:10.1016/j.jssc.2013.07.032. Bibcode: 2013JSSCh.206...91Z. 
  8. ↑ Sun, Wei; Zhu, Teng-Teng; Zhao, Biao-Chun; Huang, Ya-Xi; Mi, Jin-Xiao (2012-05-15). "Redetermination of Ce[B 5 O 8 (OH)(H 2 O)NO 3 ·2H 2 O"]. Acta Crystallographica Section E 68 (5): i33–i34. doi:10.1107/S1600536812016169. ISSN 1600-5368. PMID 22590053. PMC 3344287. http://scripts.iucr.org/cgi-bin/paper?S1600536812016169. 
  9. ↑ Ortner, Teresa S.; Huppertz, Hubert (2017-09-26). "Hydrothermal synthesis and characterization of the praseodymium borate-nitrate Pr[B5O8(OH)(H2O)0.87NO3·2H2O"]. Zeitschrift für Naturforschung B 72 (9): 677–685. doi:10.1515/znb-2017-0121. ISSN 1865-7117. http://www.degruyter.com/view/j/znb.2017.72.issue-9/znb-2017-0121/znb-2017-0121.xml. 
  10. ↑ 10.0 10.1 Katrych, Sergiy; Arakcheeva, Alla; Sienkiewicz, Andrzej; Forró, László; Ivšić, Trpimir (2020-12-15). "High-Pressure Synthesis of Rare-Earth Borate-Nitrate Crystals for Second Harmonic Generation" (in en). Inorganic Chemistry 60 (1): 286–291. doi:10.1021/acs.inorgchem.0c02909. ISSN 0020-1669. PMID 33320648. https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c02909. 
  11. ↑ 11.0 11.1 Ortner, Teresa S.; Wurst, Klaus; Joachim, Bastian; Huppertz, Hubert (August 2016). "Syntheses, Structure Elucidation, and Characterization of the Borate-Nitrates RE[B 5 O 8 (OH)(H 2 O) x NO 3 ·2H 2 O [RE = Nd ( x = 0.85), Sm ( x = 0)]: Syntheses, Structure Elucidation, and Characterization of the Borate-Nitrates RE[B 5 O 8 (OH)(H 2 O) x ]NO 3 ·2H 2 O [RE = Nd ( x = 0.85), Sm ( x = 0)]"] (in en). European Journal of Inorganic Chemistry 2016 (22): 3659–3665. doi:10.1002/ejic.201600480. http://doi.wiley.com/10.1002/ejic.201600480. 
  12. ↑ Ortner, Teresa S.; Wurst, Klaus; Hejny, Clivia; Huppertz, Hubert (January 2016). "Hydrothermal synthesis and characterization of the lutetium borate–nitrate Lu2B2O5(NO3)2·2H2O" (in en). Journal of Solid State Chemistry 233: 329–334. doi:10.1016/j.jssc.2015.11.005. Bibcode: 2016JSSCh.233..329O. 
  13. ↑ Song, Jun-Ling; Hu, Chun-Li; Xu, Xiang; Kong, Fang; Mao, Jiang-Gao (2015-03-16). "A Facile Synthetic Route to a New SHG Material with Two Types of Parallel π-Conjugated Planar Triangular Units" (in en). Angewandte Chemie 127 (12): 3750–3753. doi:10.1002/ange.201412344. Bibcode: 2015AngCh.127.3750S. http://doi.wiley.com/10.1002/ange.201412344. 
  14. ↑ Song, Jun-Ling; Hu, Chun-Li; Xu, Xiang; Kong, Fang; Mao, Jiang-Gao (2013-08-05). "Pb 2 B 3 O 5.5 (OH) 2 and [Pb 3 (B 3 O 7 )(NO 3 ): Facile Syntheses of New Lead(II) Borates by Simply Changing the pH Values of the Reaction Systems"] (in en). Inorganic Chemistry 52 (15): 8979–8986. doi:10.1021/ic401175r. ISSN 0020-1669. PMID 23834222. https://pubs.acs.org/doi/10.1021/ic401175r. 
Salts and covalent derivatives of the nitrate ion
HNO3 He
LiNO3 Be(NO3)2 B(NO3)−4 C NO−3,
NH4NO3 		O FNO3 Ne
NaNO3 Mg(NO3)2 Al(NO3)3 Si P S ClONO2 Ar
KNO3 Ca(NO3)2 Sc(NO3)3 Ti(NO3)4 VO(NO3)3 Cr(NO3)3 Mn(NO3)2 Fe(NO3)3,
Fe(NO3)2 		Co(NO3)2,
Co(NO3)3 		Ni(NO3)2 Cu(NO3)2 Zn(NO3)2 Ga(NO3)3 Ge As Se Br Kr
RbNO3 Sr(NO3)2 Y(NO3)3 Zr(NO3)4 Nb Mo Tc Ru Rh Pd(NO3)2 AgNO3 Cd(NO3)2 In Sn Sb(NO3)3 Te I Xe(NO3)2
CsNO3 Ba(NO3)2   Hf Ta W Re Os Ir Pt Au Hg2(NO3)2,
Hg(NO3)2 		Tl(NO3)3,
TlNO3 		Pb(NO3)2 Bi(NO3)3
BiO(NO3) 		Po At Rn
FrNO3 Ra(NO3)2   Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
La(NO3)3 Ce(NO3)3,
Ce(NO3)4 		Pr Nd(NO3)3 Pm Sm Eu(NO3)3 Gd(NO3)3 Tb(NO3)3 Dy Ho Er Tm Yb Lu
Ac(NO3)3 Th(NO3)4 Pa UO2(NO3)2 Np Pu Am Cm Bk Cf Es Fm Md No Lr



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