Chemistry:3-Phenylazoacetylacetone
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| Names | |
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| IUPAC name
3-phenyldiazenylpentane-2,4-dione
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| Other names
Phenyl-azo-acetylacetone; 3-(Phenylazo)pentane-2,4-dione
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| Identifiers | |
3D model (JSmol)
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| Properties | |
| C11H12N2O2 | |
| Molar mass | 204.229 g·mol−1 |
| Melting point | 96 °C (205 °F; 369 K) |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
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| Infobox references | |
Tracking categories (test):
3-Phenylazoacetylacetone (or phenyl-azo-acetylaceton) is a chemical compound[1] used as an intermediate in the preparation of biologically active compounds,[2] chelating agents,[3] and dyes.[4]
Preparation has been described as involving the gradual addition of a solution of benzenediazonium chloride exactly neutralized with sodium carbonate to a cold solution of acetylacetone in aqueous sodium carbonate.[5]
References
- ↑ Chemical Society (Great Britain) (1902). Journal - Chemical Society, London. Chemical Society.. pp. 649–. https://books.google.com/books?id=NcAwAAAAYAAJ&pg=PA649. Retrieved 23 June 2010.
- ↑ Sharma, R. N.; Dikshit, S. N.; Dubey, L.; Pandey, G.; Sharma, Harendra K. Synthesis, characterization, and biological activities of some new arylazopyrazoles. Oriental Journal of Chemistry (2009), 25(4), 923-926
- ↑ Studies on some new Ru(III) complexes using aryl-azopentane-2,4-dione and 2,6-bis(2'-benzimidazolyl)pyridine as ligands: synthesis, spectroscopic, luminescent, electrochemical and biological activities. Mishra, Lallan; Yadaw, Ajay K.; Phadke, Ratna S.; Choi, Chang S.; Araki, Koji Metal-Based Drugs (2001), 8(2), 65-71.
- ↑ Heterocyclic monoazo dyes derived from 3-cyano-2(1H)-pyridinethione. Part 2. 2-4-(Arylazo)-3,5-disubstituted-pyrazol-1-yl-carbonyl-thieno[2,3-b]pyridine derivatives. Ho, Yuh Wen; Wang, Ing Jing, Dyes and Pigments (1995), 29(4), 295-304.
- ↑ Journal of the Chemical Society, Volume 82, Part 1 Royal Society of Chemistry (Great Britain) (1902, digitized 2007). Found at Google Books. Accessed June 22, 2010.
Additional sources
- Baeyer and Claisen's phenylazoacetylacetone (Abstr., 1888, 828)
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