Chemistry:2-Methyltridecane
From HandWiki
Short description: Chemical compound
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| Preferred IUPAC name
2-Methyltridecane | |
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3D model (JSmol)
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PubChem CID
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| Properties | |
| C14H30 | |
| Molar mass | 198.394 g·mol−1 |
| Melting point | −21 °C (252 K)[1] |
| Boiling point | 121.5 °C (394.6 K)（12 Torr）[2] |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
2-Methyltridecane is an organic compound with chemical formula C14H30. It is an isomer of tetradecane. It can be produced by reducing 2,2-dimethyl-3-decylthiirane.[3] Metallic lanthanum in tetrahydrofuran can reduce 2-iodo-2-methyltridecane into 2-methyltridecane. In this reaction, the byproducts include 12,12,13,13-tetramethyltetracosane and some alkenes.[4] Adding hydrogen to 13-bromo-2-methyldecan-2-ol can produce some 2-methyltridecane. This reaction is catalyzed by Raney nickel.[5]
References
- ↑ Petrov, A. D. Synthesis and properties of branched C12-C24 paraffins. Doklady - Akademiya Nauk Azerbaidzhanskoi SSR, 1955. 11 (11): 747-755. ISSN 0002-3078.
- ↑ Petrov, Al. A.; Sergienko, S. R.; Nechitailo, N. A.; Tsedilina, A. L. Synthesis and properties of monomethyl alkanes of composition C12-16. Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1959. 1091-1097. ISSN 0002-3353.
- ↑ J.R. Schauder; J.N. Denis; A. Krief (1983). "Reduction of thiiranes to alkenes and alkanes" (in en). Tetrahedron Letters 24 (15): 1657–1660. doi:10.1016/S0040-4039(00)81737-2. https://linkinghub.elsevier.com/retrieve/pii/S0040403900817372. Retrieved 2020-06-10.
- ↑ Toshiki Nishino; Toshihisa Watanabe; Mitsuo Okada; Yutaka Nishiyama; Noboru Sonoda (February 2002). "Reduction of Organic Halides with Lanthanum Metal: A Novel Generation Method of Alkyl Radicals" (in en). The Journal of Organic Chemistry 67 (3): 966–969. doi:10.1021/jo016205n. ISSN 0022-3263. PMID 11856045. https://pubs.acs.org/doi/10.1021/jo016205n. Retrieved 2020-06-10.
- ↑ Marie E. Krafft; William J. Crooks (January 1988). "Deoxygenation of tertiary alcohols using Raney nickel" (in en). The Journal of Organic Chemistry 53 (2): 432–434. doi:10.1021/jo00237a041. ISSN 0022-3263. https://pubs.acs.org/doi/abs/10.1021/jo00237a041. Retrieved 2020-06-10.
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