Chemistry:2-Methyldodecane
From HandWiki
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| Names | |
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| Preferred IUPAC name
2-Methyldodecane | |
| Other names
Isotridecane
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| Identifiers | |
3D model (JSmol)
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| ChemSpider | |
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PubChem CID
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| Properties | |
| C13H28 | |
| Molar mass | 184.367 g·mol−1 |
| Density | 0.754 g·cm−3（20 °C）[1] |
| Boiling point | 103–104 °C (376–377 K)（10.5 Torr）[1] 227.7±3.0 °C（760 Torr）[2] |
| Hazards | |
| GHS pictograms | 
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| GHS Signal word | Danger |
| H304, H372, H373 | |
| P260, P264, P270, P301+310, P314, P331, P405, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
2-Methyldodecane, an organic compound with a chemical formula C13H28, is an isomer of tridecane. It is produced by the reaction of 1-bromodecane and diisopropyl zinc.[3] Reaction of decylmagnesium bromide and 2-bromopropane produce 2-methyldodecane too.[4] Another method to produce 2-methyldodecane is react 1-dodecene and trimethylaluminium.[5]
References
- ↑ 1.0 1.1 Bashkirov, A. N.; Shaikhutdinov, E. M.; Gilyarovskaya, L. A. Oxidation of monomethyl-substituted paraffin hydrocarbons in the liquid phase in the presence of boric acid. Doklady Akademii Nauk SSSR, 1963. 148. 1309-1311. ISSN 0002-3264.
- ↑ Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2020 ACD/Labs). Retrieved from SciFinder. [2020-06-11].
- ↑ Terao, Jun; Todo, Hirohisa; Watanabe, Hideyuki; Ikumi, Aki; Kambe, Nobuaki (2004-11-19). "Nickel-Catalyzed Cross-Coupling Reaction of Alkyl Halides with Organozinc and Grignard Reagents with 1,3,8,10-Tetraenes as Additives" (in en). Angewandte Chemie International Edition 43 (45): 6180–6182. doi:10.1002/anie.200460246. ISSN 1433-7851. PMID 15549748. https://onlinelibrary.wiley.com/doi/10.1002/anie.200460246.
- ↑ Cahiez, Gérard; Chaboche, Christophe; Duplais, Christophe; Giulliani, Arianna; Moyeux, Alban (2008-07-07). "Cobalt-Catalyzed Cross-Coupling Reaction between Functionalized Primary and Secondary Alkyl Halides and Aliphatic Grignard Reagents" (in en). Advanced Synthesis & Catalysis 350 (10): 1484–1488. doi:10.1002/adsc.200800166. https://onlinelibrary.wiley.com/doi/10.1002/adsc.200800166.
- ↑ Mark, Stefan; Gaidzik, Nikola; Doye, Sven; Enders, Markus (2009). "Organochromium complexes as catalysts for the carboalumination of unactivated terminal olefins" (in en). Dalton Transactions (25): 4875–4877. doi:10.1039/b902609f. ISSN 1477-9226. PMID 19662278. http://xlink.rsc.org/?DOI=b902609f. Retrieved 2020-06-19.
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