Chemistry:1,2-Cyclohexanedione
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| Preferred IUPAC name
Cyclohexane-1,2-dione | |
| Identifiers | |
3D model (JSmol)
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PubChem CID
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| Properties | |
| C6H8O2 | |
| Molar mass | 112.128 g·mol−1 |
| Appearance | white, waxy solid |
| Density | 1.1305 g/cm3 |
| Melting point | 40 °C |
| Boiling point | 194 °C |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
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Tracking categories (test):
1,2-Cyclohexanedione is an organic compound with the formula (CH
2)
4(CO)
2. It is one of three isomeric cyclohexanediones. It is a colorless compound that is soluble in a variety of organic solvents. It can be prepared by oxidation of cyclohexanone by selenium dioxide.[1] The enol is about 1 kcal/mol more stable than the diketo form.[2]
Numerous diimine and dioxime ligands have been prepared from this diketone.[1] It also condenses with 1,2-diamines to give diaza heterocycles.
References
- ↑ 1.0 1.1 Hach, Clifford C.; Banks, Charles V.; Diehl, Harvey (1952). "1,2-Cyclohexanedione Dioxime". Org. Synth. 32: 35. doi:10.15227/orgsyn.032.0035.
- ↑ Jana, Kalyanashis; Ganguly, Bishwajit (2018). "DFT Study to Explore the Importance of Ring Size and Effect of Solvents on the Keto–Enol Tautomerization Process of α- and β-Cyclodiones". ACS Omega 3 (7): 8429–8439. doi:10.1021/acsomega.8b01008. PMID 31458971.
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